Dichlorido(ethanol-κO)[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]copper(II)

In the title complex, [CuCl(2)(C(10)H(7)N(3)S)(C(2)H(5)OH)], the Cu(II) ion is five-coordinated in a distorted square-pyramidal geometry by two N atoms from a 2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligand, one O atom from an ethanol mol­ecule and two Cl atoms. In the crystal, O—H⋯Cl and N—H⋯Cl hydro...

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Autores principales: Li, Long, Diao, Kai-Sheng, Ding, Yu-Qiu, Tang, Jin-Niu, Wang, Dai-Yin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343892/
https://www.ncbi.nlm.nih.gov/pubmed/22589860
http://dx.doi.org/10.1107/S1600536812013037
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author Li, Long
Diao, Kai-Sheng
Ding, Yu-Qiu
Tang, Jin-Niu
Wang, Dai-Yin
author_facet Li, Long
Diao, Kai-Sheng
Ding, Yu-Qiu
Tang, Jin-Niu
Wang, Dai-Yin
author_sort Li, Long
collection PubMed
description In the title complex, [CuCl(2)(C(10)H(7)N(3)S)(C(2)H(5)OH)], the Cu(II) ion is five-coordinated in a distorted square-pyramidal geometry by two N atoms from a 2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligand, one O atom from an ethanol mol­ecule and two Cl atoms. In the crystal, O—H⋯Cl and N—H⋯Cl hydrogen bonds link the complex mol­ecules into a layer parallel to (100). π–π inter­actions between the thia­zole rings are observed [centroid–centroid distance = 3.749 (3) Å].
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spelling pubmed-33438922012-05-15 Dichlorido(ethanol-κO)[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]copper(II) Li, Long Diao, Kai-Sheng Ding, Yu-Qiu Tang, Jin-Niu Wang, Dai-Yin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuCl(2)(C(10)H(7)N(3)S)(C(2)H(5)OH)], the Cu(II) ion is five-coordinated in a distorted square-pyramidal geometry by two N atoms from a 2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligand, one O atom from an ethanol mol­ecule and two Cl atoms. In the crystal, O—H⋯Cl and N—H⋯Cl hydrogen bonds link the complex mol­ecules into a layer parallel to (100). π–π inter­actions between the thia­zole rings are observed [centroid–centroid distance = 3.749 (3) Å]. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343892/ /pubmed/22589860 http://dx.doi.org/10.1107/S1600536812013037 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Long
Diao, Kai-Sheng
Ding, Yu-Qiu
Tang, Jin-Niu
Wang, Dai-Yin
Dichlorido(ethanol-κO)[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]copper(II)
title Dichlorido(ethanol-κO)[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]copper(II)
title_full Dichlorido(ethanol-κO)[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]copper(II)
title_fullStr Dichlorido(ethanol-κO)[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]copper(II)
title_full_unstemmed Dichlorido(ethanol-κO)[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]copper(II)
title_short Dichlorido(ethanol-κO)[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]copper(II)
title_sort dichlorido(ethanol-κo)[2-(1,3-thia­zol-4-yl-κn)-1h-benzimidazole-κn (3)]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343892/
https://www.ncbi.nlm.nih.gov/pubmed/22589860
http://dx.doi.org/10.1107/S1600536812013037
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