(Acetyl­acetonato-κ(2) O,O′)carbon­yl[tris­(4-chloro­phen­yl)phosphane-κP]rhodium(I)

The title compound, [Rh(C(5)H(7)O(2))(C(18)H(12)Cl(3)P)(CO)], contains the bidentate acetyl­acetonate ligand coordinated to the Rh(I) atom, forming a chelate ring [Rh—O = 2.0327 (15) and 2.0613 (14) Å]. The Rh(I) atom is additionally coordinated by one P [Rh—P = 2.2281 (6) Å] and one carbonyl C [Rh—...

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Detalles Bibliográficos
Autores principales: Antonels, Nathan C., Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343893/
https://www.ncbi.nlm.nih.gov/pubmed/22589861
http://dx.doi.org/10.1107/S1600536812012536
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author Antonels, Nathan C.
Meijboom, Reinout
author_facet Antonels, Nathan C.
Meijboom, Reinout
author_sort Antonels, Nathan C.
collection PubMed
description The title compound, [Rh(C(5)H(7)O(2))(C(18)H(12)Cl(3)P)(CO)], contains the bidentate acetyl­acetonate ligand coordinated to the Rh(I) atom, forming a chelate ring [Rh—O = 2.0327 (15) and 2.0613 (14) Å]. The Rh(I) atom is additionally coordinated by one P [Rh—P = 2.2281 (6) Å] and one carbonyl C [Rh—C = 1.812 (2) Å] atom, resulting in a slightly distorted square-planar geometry. The mol­ecules are packed to minimize steric hindrance with the phosphanes positioned above and below the slightly distorted square geometrical plane.
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spelling pubmed-33438932012-05-15 (Acetyl­acetonato-κ(2) O,O′)carbon­yl[tris­(4-chloro­phen­yl)phosphane-κP]rhodium(I) Antonels, Nathan C. Meijboom, Reinout Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Rh(C(5)H(7)O(2))(C(18)H(12)Cl(3)P)(CO)], contains the bidentate acetyl­acetonate ligand coordinated to the Rh(I) atom, forming a chelate ring [Rh—O = 2.0327 (15) and 2.0613 (14) Å]. The Rh(I) atom is additionally coordinated by one P [Rh—P = 2.2281 (6) Å] and one carbonyl C [Rh—C = 1.812 (2) Å] atom, resulting in a slightly distorted square-planar geometry. The mol­ecules are packed to minimize steric hindrance with the phosphanes positioned above and below the slightly distorted square geometrical plane. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343893/ /pubmed/22589861 http://dx.doi.org/10.1107/S1600536812012536 Text en © Antonels and Meijboom 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Antonels, Nathan C.
Meijboom, Reinout
(Acetyl­acetonato-κ(2) O,O′)carbon­yl[tris­(4-chloro­phen­yl)phosphane-κP]rhodium(I)
title (Acetyl­acetonato-κ(2) O,O′)carbon­yl[tris­(4-chloro­phen­yl)phosphane-κP]rhodium(I)
title_full (Acetyl­acetonato-κ(2) O,O′)carbon­yl[tris­(4-chloro­phen­yl)phosphane-κP]rhodium(I)
title_fullStr (Acetyl­acetonato-κ(2) O,O′)carbon­yl[tris­(4-chloro­phen­yl)phosphane-κP]rhodium(I)
title_full_unstemmed (Acetyl­acetonato-κ(2) O,O′)carbon­yl[tris­(4-chloro­phen­yl)phosphane-κP]rhodium(I)
title_short (Acetyl­acetonato-κ(2) O,O′)carbon­yl[tris­(4-chloro­phen­yl)phosphane-κP]rhodium(I)
title_sort (acetyl­acetonato-κ(2) o,o′)carbon­yl[tris­(4-chloro­phen­yl)phosphane-κp]rhodium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343893/
https://www.ncbi.nlm.nih.gov/pubmed/22589861
http://dx.doi.org/10.1107/S1600536812012536
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