trans-Bis[(2-bromo­phen­yl)diphenyl­phosphane-κP]carbonyl­chlorido­rhodium(I)

The title compound, trans-[RhCl(C(18)H(14)BrP)(2)(CO)], has a slightly disordered square-planar geometry with the Rh ion(I) situated on an inversion the centre and carbon­yl–chloride disorder observed as a result of the crystallographic inversion symmetry. Selected geometric parameters include: Rh—P...

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Detalles Bibliográficos
Autores principales: Malan, Frederick P., Malgas-Enus, Rehana, Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343894/
https://www.ncbi.nlm.nih.gov/pubmed/22589862
http://dx.doi.org/10.1107/S1600536812012421
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author Malan, Frederick P.
Malgas-Enus, Rehana
Meijboom, Reinout
author_facet Malan, Frederick P.
Malgas-Enus, Rehana
Meijboom, Reinout
author_sort Malan, Frederick P.
collection PubMed
description The title compound, trans-[RhCl(C(18)H(14)BrP)(2)(CO)], has a slightly disordered square-planar geometry with the Rh ion(I) situated on an inversion the centre and carbon­yl–chloride disorder observed as a result of the crystallographic inversion symmetry. Selected geometric parameters include: Rh—P = 2.3430 (8) Å, Rh—Cl = 2.434 (3) Å, Rh—C = 1.722 (8) Å, P—Rh—P = 180.00 (3)°, P—Rh—Cl = 95.40 (7)°, 84.60 (7)° and Rh—C—O = 177.9 (8)°.
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spelling pubmed-33438942012-05-15 trans-Bis[(2-bromo­phen­yl)diphenyl­phosphane-κP]carbonyl­chlorido­rhodium(I) Malan, Frederick P. Malgas-Enus, Rehana Meijboom, Reinout Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, trans-[RhCl(C(18)H(14)BrP)(2)(CO)], has a slightly disordered square-planar geometry with the Rh ion(I) situated on an inversion the centre and carbon­yl–chloride disorder observed as a result of the crystallographic inversion symmetry. Selected geometric parameters include: Rh—P = 2.3430 (8) Å, Rh—Cl = 2.434 (3) Å, Rh—C = 1.722 (8) Å, P—Rh—P = 180.00 (3)°, P—Rh—Cl = 95.40 (7)°, 84.60 (7)° and Rh—C—O = 177.9 (8)°. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343894/ /pubmed/22589862 http://dx.doi.org/10.1107/S1600536812012421 Text en © Malan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Malan, Frederick P.
Malgas-Enus, Rehana
Meijboom, Reinout
trans-Bis[(2-bromo­phen­yl)diphenyl­phosphane-κP]carbonyl­chlorido­rhodium(I)
title trans-Bis[(2-bromo­phen­yl)diphenyl­phosphane-κP]carbonyl­chlorido­rhodium(I)
title_full trans-Bis[(2-bromo­phen­yl)diphenyl­phosphane-κP]carbonyl­chlorido­rhodium(I)
title_fullStr trans-Bis[(2-bromo­phen­yl)diphenyl­phosphane-κP]carbonyl­chlorido­rhodium(I)
title_full_unstemmed trans-Bis[(2-bromo­phen­yl)diphenyl­phosphane-κP]carbonyl­chlorido­rhodium(I)
title_short trans-Bis[(2-bromo­phen­yl)diphenyl­phosphane-κP]carbonyl­chlorido­rhodium(I)
title_sort trans-bis[(2-bromo­phen­yl)diphenyl­phosphane-κp]carbonyl­chlorido­rhodium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343894/
https://www.ncbi.nlm.nih.gov/pubmed/22589862
http://dx.doi.org/10.1107/S1600536812012421
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