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Diaqua­bis­(pyrazine-2-carboxamide-κ(2) N (1),O)cobalt(II) dinitrate

The asymmetric unit of the title complex, [Co(C(5)H(5)N(3)O)(2)(H(2)O)(2)](NO(3))(2), contains one half of a Co(II) cationic unit and a nitrate anion. The entire [Co(C(5)H(5)N(3)O)(2)(H(2)O)(2)](2+) cationic unit is completed by the application of inversion symmetry at the Co(II) site, generating a...

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Detalles Bibliográficos
Autores principales: Pannu, Ajay Pal Singh, Lee, Seona, Lee, Yongjae
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343896/
https://www.ncbi.nlm.nih.gov/pubmed/22589864
http://dx.doi.org/10.1107/S1600536812012573
Descripción
Sumario:The asymmetric unit of the title complex, [Co(C(5)H(5)N(3)O)(2)(H(2)O)(2)](NO(3))(2), contains one half of a Co(II) cationic unit and a nitrate anion. The entire [Co(C(5)H(5)N(3)O)(2)(H(2)O)(2)](2+) cationic unit is completed by the application of inversion symmetry at the Co(II) site, generating a six-coordinate distorted octa­hedral environment for the metal ion. The chelating pyrazine-2-carboxamide mol­ecules are bound to cobalt via N and O atoms, forming a square plane, while the remaining two trans positions in the octa­hedron are occupied by two coordinated water mol­ecules.