Diaqua­bis­(pyrazine-2-carboxamide-κ(2) N (1),O)cobalt(II) dinitrate

The asymmetric unit of the title complex, [Co(C(5)H(5)N(3)O)(2)(H(2)O)(2)](NO(3))(2), contains one half of a Co(II) cationic unit and a nitrate anion. The entire [Co(C(5)H(5)N(3)O)(2)(H(2)O)(2)](2+) cationic unit is completed by the application of inversion symmetry at the Co(II) site, generating a...

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Detalles Bibliográficos
Autores principales: Pannu, Ajay Pal Singh, Lee, Seona, Lee, Yongjae
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343896/
https://www.ncbi.nlm.nih.gov/pubmed/22589864
http://dx.doi.org/10.1107/S1600536812012573
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author Pannu, Ajay Pal Singh
Lee, Seona
Lee, Yongjae
author_facet Pannu, Ajay Pal Singh
Lee, Seona
Lee, Yongjae
author_sort Pannu, Ajay Pal Singh
collection PubMed
description The asymmetric unit of the title complex, [Co(C(5)H(5)N(3)O)(2)(H(2)O)(2)](NO(3))(2), contains one half of a Co(II) cationic unit and a nitrate anion. The entire [Co(C(5)H(5)N(3)O)(2)(H(2)O)(2)](2+) cationic unit is completed by the application of inversion symmetry at the Co(II) site, generating a six-coordinate distorted octa­hedral environment for the metal ion. The chelating pyrazine-2-carboxamide mol­ecules are bound to cobalt via N and O atoms, forming a square plane, while the remaining two trans positions in the octa­hedron are occupied by two coordinated water mol­ecules.
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spelling pubmed-33438962012-05-15 Diaqua­bis­(pyrazine-2-carboxamide-κ(2) N (1),O)cobalt(II) dinitrate Pannu, Ajay Pal Singh Lee, Seona Lee, Yongjae Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Co(C(5)H(5)N(3)O)(2)(H(2)O)(2)](NO(3))(2), contains one half of a Co(II) cationic unit and a nitrate anion. The entire [Co(C(5)H(5)N(3)O)(2)(H(2)O)(2)](2+) cationic unit is completed by the application of inversion symmetry at the Co(II) site, generating a six-coordinate distorted octa­hedral environment for the metal ion. The chelating pyrazine-2-carboxamide mol­ecules are bound to cobalt via N and O atoms, forming a square plane, while the remaining two trans positions in the octa­hedron are occupied by two coordinated water mol­ecules. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343896/ /pubmed/22589864 http://dx.doi.org/10.1107/S1600536812012573 Text en © Pannu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pannu, Ajay Pal Singh
Lee, Seona
Lee, Yongjae
Diaqua­bis­(pyrazine-2-carboxamide-κ(2) N (1),O)cobalt(II) dinitrate
title Diaqua­bis­(pyrazine-2-carboxamide-κ(2) N (1),O)cobalt(II) dinitrate
title_full Diaqua­bis­(pyrazine-2-carboxamide-κ(2) N (1),O)cobalt(II) dinitrate
title_fullStr Diaqua­bis­(pyrazine-2-carboxamide-κ(2) N (1),O)cobalt(II) dinitrate
title_full_unstemmed Diaqua­bis­(pyrazine-2-carboxamide-κ(2) N (1),O)cobalt(II) dinitrate
title_short Diaqua­bis­(pyrazine-2-carboxamide-κ(2) N (1),O)cobalt(II) dinitrate
title_sort diaqua­bis­(pyrazine-2-carboxamide-κ(2) n (1),o)cobalt(ii) dinitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343896/
https://www.ncbi.nlm.nih.gov/pubmed/22589864
http://dx.doi.org/10.1107/S1600536812012573
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