{5,5′-Dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}palladium(II)

In the title compound, [Pd(C(21)H(24)N(2)O(4))], the complete mol­ecule is generated by crystallographic mirror symmetry with the Pd and three C atoms lying on the mirror plane. The Pd—O and Pd—N distances are 1.9932 (6) and 2.0029 (7) Å, respectively. The dihedral angle between two benzene rings of...

Descripción completa

Detalles Bibliográficos
Autores principales: Che Soh, Siti Kamilah, Shamsuddin, Mustaffa, Rosli, Mohd Mustaqim, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343897/
https://www.ncbi.nlm.nih.gov/pubmed/22589865
http://dx.doi.org/10.1107/S1600536812013128
Descripción
Sumario:In the title compound, [Pd(C(21)H(24)N(2)O(4))], the complete mol­ecule is generated by crystallographic mirror symmetry with the Pd and three C atoms lying on the mirror plane. The Pd—O and Pd—N distances are 1.9932 (6) and 2.0029 (7) Å, respectively. The dihedral angle between two benzene rings of the ligand is 79.21 (4)°. In the crystal, C—H⋯O hydrogen bonds link the mol­ecules into layers parallel to the ab plane. These planes are further connected by C—H⋯O inter­actions, forming a three-dimensional network.

Ejemplares similares