{5,5′-Dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}palladium(II)

In the title compound, [Pd(C(21)H(24)N(2)O(4))], the complete mol­ecule is generated by crystallographic mirror symmetry with the Pd and three C atoms lying on the mirror plane. The Pd—O and Pd—N distances are 1.9932 (6) and 2.0029 (7) Å, respectively. The dihedral angle between two benzene rings of...

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Autores principales: Che Soh, Siti Kamilah, Shamsuddin, Mustaffa, Rosli, Mohd Mustaqim, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343897/
https://www.ncbi.nlm.nih.gov/pubmed/22589865
http://dx.doi.org/10.1107/S1600536812013128
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author Che Soh, Siti Kamilah
Shamsuddin, Mustaffa
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_facet Che Soh, Siti Kamilah
Shamsuddin, Mustaffa
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_sort Che Soh, Siti Kamilah
collection PubMed
description In the title compound, [Pd(C(21)H(24)N(2)O(4))], the complete mol­ecule is generated by crystallographic mirror symmetry with the Pd and three C atoms lying on the mirror plane. The Pd—O and Pd—N distances are 1.9932 (6) and 2.0029 (7) Å, respectively. The dihedral angle between two benzene rings of the ligand is 79.21 (4)°. In the crystal, C—H⋯O hydrogen bonds link the mol­ecules into layers parallel to the ab plane. These planes are further connected by C—H⋯O inter­actions, forming a three-dimensional network.
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spelling pubmed-33438972012-05-15 {5,5′-Dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}palladium(II) Che Soh, Siti Kamilah Shamsuddin, Mustaffa Rosli, Mohd Mustaqim Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(C(21)H(24)N(2)O(4))], the complete mol­ecule is generated by crystallographic mirror symmetry with the Pd and three C atoms lying on the mirror plane. The Pd—O and Pd—N distances are 1.9932 (6) and 2.0029 (7) Å, respectively. The dihedral angle between two benzene rings of the ligand is 79.21 (4)°. In the crystal, C—H⋯O hydrogen bonds link the mol­ecules into layers parallel to the ab plane. These planes are further connected by C—H⋯O inter­actions, forming a three-dimensional network. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343897/ /pubmed/22589865 http://dx.doi.org/10.1107/S1600536812013128 Text en © Che Soh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Che Soh, Siti Kamilah
Shamsuddin, Mustaffa
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
{5,5′-Dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}palladium(II)
title {5,5′-Dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}palladium(II)
title_full {5,5′-Dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}palladium(II)
title_fullStr {5,5′-Dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}palladium(II)
title_full_unstemmed {5,5′-Dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}palladium(II)
title_short {5,5′-Dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}palladium(II)
title_sort {5,5′-dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343897/
https://www.ncbi.nlm.nih.gov/pubmed/22589865
http://dx.doi.org/10.1107/S1600536812013128
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