catena-Poly[[bis­(pyridine-3-carb­oxy­lic acid-κN)mercury(II)]-di-μ-chlorido]

In the title compound, [HgCl(2)(C(6)H(5)NO(2))(2)](n), the Hg(II) cation is located on an inversion center and is six-coordinated in a distorted octa­hedral geometry by two N atoms from two pyridine-3-carb­oxy­lic acid mol­ecules and four bridging Cl(−) anions. The bridging function of the Cl(−) ani...

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Detalles Bibliográficos
Autores principales: Shirvan, Sadif A., Haydari Dezfuli, Sara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343898/
https://www.ncbi.nlm.nih.gov/pubmed/22589866
http://dx.doi.org/10.1107/S1600536812012986
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author Shirvan, Sadif A.
Haydari Dezfuli, Sara
author_facet Shirvan, Sadif A.
Haydari Dezfuli, Sara
author_sort Shirvan, Sadif A.
collection PubMed
description In the title compound, [HgCl(2)(C(6)H(5)NO(2))(2)](n), the Hg(II) cation is located on an inversion center and is six-coordinated in a distorted octa­hedral geometry by two N atoms from two pyridine-3-carb­oxy­lic acid mol­ecules and four bridging Cl(−) anions. The bridging function of the Cl(−) anions leads to polymeric chains running along the a axis. One Hg—Cl bond is much longer than the other. In the crystal, O—H⋯O and weak C—H⋯Cl hydrogen bonds are observed.
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spelling pubmed-33438982012-05-15 catena-Poly[[bis­(pyridine-3-carb­oxy­lic acid-κN)mercury(II)]-di-μ-chlorido] Shirvan, Sadif A. Haydari Dezfuli, Sara Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [HgCl(2)(C(6)H(5)NO(2))(2)](n), the Hg(II) cation is located on an inversion center and is six-coordinated in a distorted octa­hedral geometry by two N atoms from two pyridine-3-carb­oxy­lic acid mol­ecules and four bridging Cl(−) anions. The bridging function of the Cl(−) anions leads to polymeric chains running along the a axis. One Hg—Cl bond is much longer than the other. In the crystal, O—H⋯O and weak C—H⋯Cl hydrogen bonds are observed. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343898/ /pubmed/22589866 http://dx.doi.org/10.1107/S1600536812012986 Text en © Shirvan and Haydari Dezfuli 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shirvan, Sadif A.
Haydari Dezfuli, Sara
catena-Poly[[bis­(pyridine-3-carb­oxy­lic acid-κN)mercury(II)]-di-μ-chlorido]
title catena-Poly[[bis­(pyridine-3-carb­oxy­lic acid-κN)mercury(II)]-di-μ-chlorido]
title_full catena-Poly[[bis­(pyridine-3-carb­oxy­lic acid-κN)mercury(II)]-di-μ-chlorido]
title_fullStr catena-Poly[[bis­(pyridine-3-carb­oxy­lic acid-κN)mercury(II)]-di-μ-chlorido]
title_full_unstemmed catena-Poly[[bis­(pyridine-3-carb­oxy­lic acid-κN)mercury(II)]-di-μ-chlorido]
title_short catena-Poly[[bis­(pyridine-3-carb­oxy­lic acid-κN)mercury(II)]-di-μ-chlorido]
title_sort catena-poly[[bis­(pyridine-3-carb­oxy­lic acid-κn)mercury(ii)]-di-μ-chlorido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343898/
https://www.ncbi.nlm.nih.gov/pubmed/22589866
http://dx.doi.org/10.1107/S1600536812012986
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