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Aqua­(2,2′-bipyridine-κ(2) N,N′){(E)-[(5-chloro-2-oxidobenzyl­idene)amino-κ(2) N,O]methane­sulfonato-κO}zinc

In the title compound, [Zn(C(8)H(6)ClNO(4)S)(C(10)H(8)N(2))(H(2)O)], the Zn(II) atom is six-coordinated by two O atoms and one N atom from a tridentate Schiff base ligand and two N atoms from a chelating 2,2′-bipyridine ligand and one water mol­ecule, forming a slightly distorted octa­hedral geometr...

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Detalles Bibliográficos
Autores principales: Deng, Yi-Fang, Nie, Xue, Zhang, Chun-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343899/
https://www.ncbi.nlm.nih.gov/pubmed/22589867
http://dx.doi.org/10.1107/S1600536812013050
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author Deng, Yi-Fang
Nie, Xue
Zhang, Chun-Hua
author_facet Deng, Yi-Fang
Nie, Xue
Zhang, Chun-Hua
author_sort Deng, Yi-Fang
collection PubMed
description In the title compound, [Zn(C(8)H(6)ClNO(4)S)(C(10)H(8)N(2))(H(2)O)], the Zn(II) atom is six-coordinated by two O atoms and one N atom from a tridentate Schiff base ligand and two N atoms from a chelating 2,2′-bipyridine ligand and one water mol­ecule, forming a slightly distorted octa­hedral geometry. In the crystal, O—H⋯O hydrogen bonds link pairs of complex mol­ecules into dimers. An intra­molecular O—H⋯O hydrogen bond is also present.
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spelling pubmed-33438992012-05-15 Aqua­(2,2′-bipyridine-κ(2) N,N′){(E)-[(5-chloro-2-oxidobenzyl­idene)amino-κ(2) N,O]methane­sulfonato-κO}zinc Deng, Yi-Fang Nie, Xue Zhang, Chun-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(8)H(6)ClNO(4)S)(C(10)H(8)N(2))(H(2)O)], the Zn(II) atom is six-coordinated by two O atoms and one N atom from a tridentate Schiff base ligand and two N atoms from a chelating 2,2′-bipyridine ligand and one water mol­ecule, forming a slightly distorted octa­hedral geometry. In the crystal, O—H⋯O hydrogen bonds link pairs of complex mol­ecules into dimers. An intra­molecular O—H⋯O hydrogen bond is also present. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343899/ /pubmed/22589867 http://dx.doi.org/10.1107/S1600536812013050 Text en © Deng et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Deng, Yi-Fang
Nie, Xue
Zhang, Chun-Hua
Aqua­(2,2′-bipyridine-κ(2) N,N′){(E)-[(5-chloro-2-oxidobenzyl­idene)amino-κ(2) N,O]methane­sulfonato-κO}zinc
title Aqua­(2,2′-bipyridine-κ(2) N,N′){(E)-[(5-chloro-2-oxidobenzyl­idene)amino-κ(2) N,O]methane­sulfonato-κO}zinc
title_full Aqua­(2,2′-bipyridine-κ(2) N,N′){(E)-[(5-chloro-2-oxidobenzyl­idene)amino-κ(2) N,O]methane­sulfonato-κO}zinc
title_fullStr Aqua­(2,2′-bipyridine-κ(2) N,N′){(E)-[(5-chloro-2-oxidobenzyl­idene)amino-κ(2) N,O]methane­sulfonato-κO}zinc
title_full_unstemmed Aqua­(2,2′-bipyridine-κ(2) N,N′){(E)-[(5-chloro-2-oxidobenzyl­idene)amino-κ(2) N,O]methane­sulfonato-κO}zinc
title_short Aqua­(2,2′-bipyridine-κ(2) N,N′){(E)-[(5-chloro-2-oxidobenzyl­idene)amino-κ(2) N,O]methane­sulfonato-κO}zinc
title_sort aqua­(2,2′-bipyridine-κ(2) n,n′){(e)-[(5-chloro-2-oxidobenzyl­idene)amino-κ(2) n,o]methane­sulfonato-κo}zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343899/
https://www.ncbi.nlm.nih.gov/pubmed/22589867
http://dx.doi.org/10.1107/S1600536812013050
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