Cargando…
Aqua(2,2′-bipyridine-κ(2) N,N′){(E)-[(5-chloro-2-oxidobenzylidene)amino-κ(2) N,O]methanesulfonato-κO}zinc
In the title compound, [Zn(C(8)H(6)ClNO(4)S)(C(10)H(8)N(2))(H(2)O)], the Zn(II) atom is six-coordinated by two O atoms and one N atom from a tridentate Schiff base ligand and two N atoms from a chelating 2,2′-bipyridine ligand and one water molecule, forming a slightly distorted octahedral geometr...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343899/ https://www.ncbi.nlm.nih.gov/pubmed/22589867 http://dx.doi.org/10.1107/S1600536812013050 |
_version_ | 1782231869807394816 |
---|---|
author | Deng, Yi-Fang Nie, Xue Zhang, Chun-Hua |
author_facet | Deng, Yi-Fang Nie, Xue Zhang, Chun-Hua |
author_sort | Deng, Yi-Fang |
collection | PubMed |
description | In the title compound, [Zn(C(8)H(6)ClNO(4)S)(C(10)H(8)N(2))(H(2)O)], the Zn(II) atom is six-coordinated by two O atoms and one N atom from a tridentate Schiff base ligand and two N atoms from a chelating 2,2′-bipyridine ligand and one water molecule, forming a slightly distorted octahedral geometry. In the crystal, O—H⋯O hydrogen bonds link pairs of complex molecules into dimers. An intramolecular O—H⋯O hydrogen bond is also present. |
format | Online Article Text |
id | pubmed-3343899 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33438992012-05-15 Aqua(2,2′-bipyridine-κ(2) N,N′){(E)-[(5-chloro-2-oxidobenzylidene)amino-κ(2) N,O]methanesulfonato-κO}zinc Deng, Yi-Fang Nie, Xue Zhang, Chun-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(8)H(6)ClNO(4)S)(C(10)H(8)N(2))(H(2)O)], the Zn(II) atom is six-coordinated by two O atoms and one N atom from a tridentate Schiff base ligand and two N atoms from a chelating 2,2′-bipyridine ligand and one water molecule, forming a slightly distorted octahedral geometry. In the crystal, O—H⋯O hydrogen bonds link pairs of complex molecules into dimers. An intramolecular O—H⋯O hydrogen bond is also present. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343899/ /pubmed/22589867 http://dx.doi.org/10.1107/S1600536812013050 Text en © Deng et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Deng, Yi-Fang Nie, Xue Zhang, Chun-Hua Aqua(2,2′-bipyridine-κ(2) N,N′){(E)-[(5-chloro-2-oxidobenzylidene)amino-κ(2) N,O]methanesulfonato-κO}zinc |
title | Aqua(2,2′-bipyridine-κ(2)
N,N′){(E)-[(5-chloro-2-oxidobenzylidene)amino-κ(2)
N,O]methanesulfonato-κO}zinc |
title_full | Aqua(2,2′-bipyridine-κ(2)
N,N′){(E)-[(5-chloro-2-oxidobenzylidene)amino-κ(2)
N,O]methanesulfonato-κO}zinc |
title_fullStr | Aqua(2,2′-bipyridine-κ(2)
N,N′){(E)-[(5-chloro-2-oxidobenzylidene)amino-κ(2)
N,O]methanesulfonato-κO}zinc |
title_full_unstemmed | Aqua(2,2′-bipyridine-κ(2)
N,N′){(E)-[(5-chloro-2-oxidobenzylidene)amino-κ(2)
N,O]methanesulfonato-κO}zinc |
title_short | Aqua(2,2′-bipyridine-κ(2)
N,N′){(E)-[(5-chloro-2-oxidobenzylidene)amino-κ(2)
N,O]methanesulfonato-κO}zinc |
title_sort | aqua(2,2′-bipyridine-κ(2)
n,n′){(e)-[(5-chloro-2-oxidobenzylidene)amino-κ(2)
n,o]methanesulfonato-κo}zinc |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343899/ https://www.ncbi.nlm.nih.gov/pubmed/22589867 http://dx.doi.org/10.1107/S1600536812013050 |
work_keys_str_mv | AT dengyifang aqua22bipyridinek2nne5chloro2oxidobenzylideneaminok2nomethanesulfonatokozinc AT niexue aqua22bipyridinek2nne5chloro2oxidobenzylideneaminok2nomethanesulfonatokozinc AT zhangchunhua aqua22bipyridinek2nne5chloro2oxidobenzylideneaminok2nomethanesulfonatokozinc |