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Bis(di-2-pyridylamine-κ(2) N (2),N (2’))platinum(II) dibromide monohydrate
The asymmetric unit of the title compound, [Pt(C(10)H(9)N(3))(2)]Br(2)·H(2)O, contains two crystallographically independent half-molecules of the cationic Pt(II) complex, two Br(−) anions and a lattice water molecule; an inversion centre is located at the centroid of each complex. Each Pt(II) ion...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343900/ https://www.ncbi.nlm.nih.gov/pubmed/22589868 http://dx.doi.org/10.1107/S1600536812013062 |
Sumario: | The asymmetric unit of the title compound, [Pt(C(10)H(9)N(3))(2)]Br(2)·H(2)O, contains two crystallographically independent half-molecules of the cationic Pt(II) complex, two Br(−) anions and a lattice water molecule; an inversion centre is located at the centroid of each complex. Each Pt(II) ion is four-coordinated in an essentially square-planar environment by four pyridine N atoms derived from the two chelating di-2-pyridylamine (dpa) ligands, and the PtN(4) unit is exactly planar. The chelate ring formed by the dpa ligand displays a boat conformation, with dihedral angles between the pyridine rings of 35.9 (2) and 41.0 (2)°. The complex cations, Br(−) anions and solvent water molecules are linked by O—H⋯Br, N—H⋯Br, C—H⋯O and C—H⋯Br hydrogen bonds, forming a three-dimensional network. |
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