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Bis(di-2-pyridylamine-κ(2) N (2),N (2’))platinum(II) dibromide monohydrate
The asymmetric unit of the title compound, [Pt(C(10)H(9)N(3))(2)]Br(2)·H(2)O, contains two crystallographically independent half-molecules of the cationic Pt(II) complex, two Br(−) anions and a lattice water molecule; an inversion centre is located at the centroid of each complex. Each Pt(II) ion...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343900/ https://www.ncbi.nlm.nih.gov/pubmed/22589868 http://dx.doi.org/10.1107/S1600536812013062 |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | The asymmetric unit of the title compound, [Pt(C(10)H(9)N(3))(2)]Br(2)·H(2)O, contains two crystallographically independent half-molecules of the cationic Pt(II) complex, two Br(−) anions and a lattice water molecule; an inversion centre is located at the centroid of each complex. Each Pt(II) ion is four-coordinated in an essentially square-planar environment by four pyridine N atoms derived from the two chelating di-2-pyridylamine (dpa) ligands, and the PtN(4) unit is exactly planar. The chelate ring formed by the dpa ligand displays a boat conformation, with dihedral angles between the pyridine rings of 35.9 (2) and 41.0 (2)°. The complex cations, Br(−) anions and solvent water molecules are linked by O—H⋯Br, N—H⋯Br, C—H⋯O and C—H⋯Br hydrogen bonds, forming a three-dimensional network. |
format | Online Article Text |
id | pubmed-3343900 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33439002012-05-15 Bis(di-2-pyridylamine-κ(2) N (2),N (2’))platinum(II) dibromide monohydrate Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Pt(C(10)H(9)N(3))(2)]Br(2)·H(2)O, contains two crystallographically independent half-molecules of the cationic Pt(II) complex, two Br(−) anions and a lattice water molecule; an inversion centre is located at the centroid of each complex. Each Pt(II) ion is four-coordinated in an essentially square-planar environment by four pyridine N atoms derived from the two chelating di-2-pyridylamine (dpa) ligands, and the PtN(4) unit is exactly planar. The chelate ring formed by the dpa ligand displays a boat conformation, with dihedral angles between the pyridine rings of 35.9 (2) and 41.0 (2)°. The complex cations, Br(−) anions and solvent water molecules are linked by O—H⋯Br, N—H⋯Br, C—H⋯O and C—H⋯Br hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343900/ /pubmed/22589868 http://dx.doi.org/10.1107/S1600536812013062 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang Bis(di-2-pyridylamine-κ(2) N (2),N (2’))platinum(II) dibromide monohydrate |
title | Bis(di-2-pyridylamine-κ(2)
N
(2),N
(2’))platinum(II) dibromide monohydrate |
title_full | Bis(di-2-pyridylamine-κ(2)
N
(2),N
(2’))platinum(II) dibromide monohydrate |
title_fullStr | Bis(di-2-pyridylamine-κ(2)
N
(2),N
(2’))platinum(II) dibromide monohydrate |
title_full_unstemmed | Bis(di-2-pyridylamine-κ(2)
N
(2),N
(2’))platinum(II) dibromide monohydrate |
title_short | Bis(di-2-pyridylamine-κ(2)
N
(2),N
(2’))platinum(II) dibromide monohydrate |
title_sort | bis(di-2-pyridylamine-κ(2)
n
(2),n
(2’))platinum(ii) dibromide monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343900/ https://www.ncbi.nlm.nih.gov/pubmed/22589868 http://dx.doi.org/10.1107/S1600536812013062 |
work_keys_str_mv | AT hakwang bisdi2pyridylaminek2n2n2platinumiidibromidemonohydrate |