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Bis(di-2-pyridyl­amine-κ(2) N (2),N (2’))platinum(II) dibromide monohydrate

The asymmetric unit of the title compound, [Pt(C(10)H(9)N(3))(2)]Br(2)·H(2)O, contains two crystallographically independent half-mol­ecules of the cationic Pt(II) complex, two Br(−) anions and a lattice water mol­ecule; an inversion centre is located at the centroid of each complex. Each Pt(II) ion...

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Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343900/
https://www.ncbi.nlm.nih.gov/pubmed/22589868
http://dx.doi.org/10.1107/S1600536812013062
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The asymmetric unit of the title compound, [Pt(C(10)H(9)N(3))(2)]Br(2)·H(2)O, contains two crystallographically independent half-mol­ecules of the cationic Pt(II) complex, two Br(−) anions and a lattice water mol­ecule; an inversion centre is located at the centroid of each complex. Each Pt(II) ion is four-coordinated in an essentially square-planar environment by four pyridine N atoms derived from the two chelating di-2-pyridyl­amine (dpa) ligands, and the PtN(4) unit is exactly planar. The chelate ring formed by the dpa ligand displays a boat conformation, with dihedral angles between the pyridine rings of 35.9 (2) and 41.0 (2)°. The complex cations, Br(−) anions and solvent water mol­ecules are linked by O—H⋯Br, N—H⋯Br, C—H⋯O and C—H⋯Br hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-33439002012-05-15 Bis(di-2-pyridyl­amine-κ(2) N (2),N (2’))platinum(II) dibromide monohydrate Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Pt(C(10)H(9)N(3))(2)]Br(2)·H(2)O, contains two crystallographically independent half-mol­ecules of the cationic Pt(II) complex, two Br(−) anions and a lattice water mol­ecule; an inversion centre is located at the centroid of each complex. Each Pt(II) ion is four-coordinated in an essentially square-planar environment by four pyridine N atoms derived from the two chelating di-2-pyridyl­amine (dpa) ligands, and the PtN(4) unit is exactly planar. The chelate ring formed by the dpa ligand displays a boat conformation, with dihedral angles between the pyridine rings of 35.9 (2) and 41.0 (2)°. The complex cations, Br(−) anions and solvent water mol­ecules are linked by O—H⋯Br, N—H⋯Br, C—H⋯O and C—H⋯Br hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343900/ /pubmed/22589868 http://dx.doi.org/10.1107/S1600536812013062 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Bis(di-2-pyridyl­amine-κ(2) N (2),N (2’))platinum(II) dibromide monohydrate
title Bis(di-2-pyridyl­amine-κ(2) N (2),N (2’))platinum(II) dibromide monohydrate
title_full Bis(di-2-pyridyl­amine-κ(2) N (2),N (2’))platinum(II) dibromide monohydrate
title_fullStr Bis(di-2-pyridyl­amine-κ(2) N (2),N (2’))platinum(II) dibromide monohydrate
title_full_unstemmed Bis(di-2-pyridyl­amine-κ(2) N (2),N (2’))platinum(II) dibromide monohydrate
title_short Bis(di-2-pyridyl­amine-κ(2) N (2),N (2’))platinum(II) dibromide monohydrate
title_sort bis(di-2-pyridyl­amine-κ(2) n (2),n (2’))platinum(ii) dibromide monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343900/
https://www.ncbi.nlm.nih.gov/pubmed/22589868
http://dx.doi.org/10.1107/S1600536812013062
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