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Bis(azido-κN)(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II)

In the title complex, [Pd(N(3))(2)(C(10)H(9)N(3))], the Pd(II) ion is in a slightly distorted square-planar coordination environment. The ligator atoms comprise the two pyridine N atoms of the chelating di-2-pyridyl­amine (dpa) ligand and two N atoms from two azide anions. The dpa ligand coordinates...

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Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343901/
https://www.ncbi.nlm.nih.gov/pubmed/22589869
http://dx.doi.org/10.1107/S1600536812013074
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the title complex, [Pd(N(3))(2)(C(10)H(9)N(3))], the Pd(II) ion is in a slightly distorted square-planar coordination environment. The ligator atoms comprise the two pyridine N atoms of the chelating di-2-pyridyl­amine (dpa) ligand and two N atoms from two azide anions. The dpa ligand coordinates the Pd atom in a boat conformation, the dihedral angle between the pyridine rings being 24.4 (1)°. The pyridine rings are somewhat inclined to the least-squares plane of the PdN(4) unit, making dihedral angles of 29.02 (9) and 26.47 (9)°. The azide ligands are slightly bent, with N—N—N angles of 173.0 (4) and 174.2 (4)°. In the crystal, mol­ecules are connected by N—H⋯N and C—H⋯N hydrogen bonds, forming chains along the c axis. When viewed down the b axis, successive chains are stacked in opposite directions. Intra­molecular C—H⋯N hydrogen bonds are also observed.
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spelling pubmed-33439012012-05-15 Bis(azido-κN)(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pd(N(3))(2)(C(10)H(9)N(3))], the Pd(II) ion is in a slightly distorted square-planar coordination environment. The ligator atoms comprise the two pyridine N atoms of the chelating di-2-pyridyl­amine (dpa) ligand and two N atoms from two azide anions. The dpa ligand coordinates the Pd atom in a boat conformation, the dihedral angle between the pyridine rings being 24.4 (1)°. The pyridine rings are somewhat inclined to the least-squares plane of the PdN(4) unit, making dihedral angles of 29.02 (9) and 26.47 (9)°. The azide ligands are slightly bent, with N—N—N angles of 173.0 (4) and 174.2 (4)°. In the crystal, mol­ecules are connected by N—H⋯N and C—H⋯N hydrogen bonds, forming chains along the c axis. When viewed down the b axis, successive chains are stacked in opposite directions. Intra­molecular C—H⋯N hydrogen bonds are also observed. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343901/ /pubmed/22589869 http://dx.doi.org/10.1107/S1600536812013074 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Bis(azido-κN)(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II)
title Bis(azido-κN)(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II)
title_full Bis(azido-κN)(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II)
title_fullStr Bis(azido-κN)(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II)
title_full_unstemmed Bis(azido-κN)(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II)
title_short Bis(azido-κN)(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II)
title_sort bis(azido-κn)(di-2-pyridyl­amine-κ(2) n (2),n (2′))palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343901/
https://www.ncbi.nlm.nih.gov/pubmed/22589869
http://dx.doi.org/10.1107/S1600536812013074
work_keys_str_mv AT hakwang bisazidokndi2pyridylaminek2n2n2palladiumii