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Bis(azido-κN)(di-2-pyridylamine-κ(2) N (2),N (2′))palladium(II)
In the title complex, [Pd(N(3))(2)(C(10)H(9)N(3))], the Pd(II) ion is in a slightly distorted square-planar coordination environment. The ligator atoms comprise the two pyridine N atoms of the chelating di-2-pyridylamine (dpa) ligand and two N atoms from two azide anions. The dpa ligand coordinates...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343901/ https://www.ncbi.nlm.nih.gov/pubmed/22589869 http://dx.doi.org/10.1107/S1600536812013074 |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | In the title complex, [Pd(N(3))(2)(C(10)H(9)N(3))], the Pd(II) ion is in a slightly distorted square-planar coordination environment. The ligator atoms comprise the two pyridine N atoms of the chelating di-2-pyridylamine (dpa) ligand and two N atoms from two azide anions. The dpa ligand coordinates the Pd atom in a boat conformation, the dihedral angle between the pyridine rings being 24.4 (1)°. The pyridine rings are somewhat inclined to the least-squares plane of the PdN(4) unit, making dihedral angles of 29.02 (9) and 26.47 (9)°. The azide ligands are slightly bent, with N—N—N angles of 173.0 (4) and 174.2 (4)°. In the crystal, molecules are connected by N—H⋯N and C—H⋯N hydrogen bonds, forming chains along the c axis. When viewed down the b axis, successive chains are stacked in opposite directions. Intramolecular C—H⋯N hydrogen bonds are also observed. |
format | Online Article Text |
id | pubmed-3343901 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33439012012-05-15 Bis(azido-κN)(di-2-pyridylamine-κ(2) N (2),N (2′))palladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pd(N(3))(2)(C(10)H(9)N(3))], the Pd(II) ion is in a slightly distorted square-planar coordination environment. The ligator atoms comprise the two pyridine N atoms of the chelating di-2-pyridylamine (dpa) ligand and two N atoms from two azide anions. The dpa ligand coordinates the Pd atom in a boat conformation, the dihedral angle between the pyridine rings being 24.4 (1)°. The pyridine rings are somewhat inclined to the least-squares plane of the PdN(4) unit, making dihedral angles of 29.02 (9) and 26.47 (9)°. The azide ligands are slightly bent, with N—N—N angles of 173.0 (4) and 174.2 (4)°. In the crystal, molecules are connected by N—H⋯N and C—H⋯N hydrogen bonds, forming chains along the c axis. When viewed down the b axis, successive chains are stacked in opposite directions. Intramolecular C—H⋯N hydrogen bonds are also observed. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343901/ /pubmed/22589869 http://dx.doi.org/10.1107/S1600536812013074 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang Bis(azido-κN)(di-2-pyridylamine-κ(2) N (2),N (2′))palladium(II) |
title | Bis(azido-κN)(di-2-pyridylamine-κ(2)
N
(2),N
(2′))palladium(II) |
title_full | Bis(azido-κN)(di-2-pyridylamine-κ(2)
N
(2),N
(2′))palladium(II) |
title_fullStr | Bis(azido-κN)(di-2-pyridylamine-κ(2)
N
(2),N
(2′))palladium(II) |
title_full_unstemmed | Bis(azido-κN)(di-2-pyridylamine-κ(2)
N
(2),N
(2′))palladium(II) |
title_short | Bis(azido-κN)(di-2-pyridylamine-κ(2)
N
(2),N
(2′))palladium(II) |
title_sort | bis(azido-κn)(di-2-pyridylamine-κ(2)
n
(2),n
(2′))palladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343901/ https://www.ncbi.nlm.nih.gov/pubmed/22589869 http://dx.doi.org/10.1107/S1600536812013074 |
work_keys_str_mv | AT hakwang bisazidokndi2pyridylaminek2n2n2palladiumii |