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catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN (3))-1,2,3-triazol-1-ido-κ(2) N (1):N (3)]
In the title complex, [Zn(C(10)H(8)N(5))Cl](n), the Zn(II) ion is four-coordinated by one Cl atom and three N atoms from two in situ-generated deprotonated 5-(1-methyl-1H-benzimidazol-2-yl-κN (3))-1,2,3-triazol-1-ide ligands in a slightly distorted tetrahedral geometry. The Zn(II) ions are bridged...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343902/ https://www.ncbi.nlm.nih.gov/pubmed/22589870 http://dx.doi.org/10.1107/S1600536812012706 |
Sumario: | In the title complex, [Zn(C(10)H(8)N(5))Cl](n), the Zn(II) ion is four-coordinated by one Cl atom and three N atoms from two in situ-generated deprotonated 5-(1-methyl-1H-benzimidazol-2-yl-κN (3))-1,2,3-triazol-1-ide ligands in a slightly distorted tetrahedral geometry. The Zn(II) ions are bridged by the ligands, forming a helical chain along [001]. C—H⋯N and C—H⋯Cl hydrogen bonds and π–π interactions between the imidazole rings [centroid–centroid distance = 3.4244 (10) Å] assemble the chains into a three-dimensional supramolecular network. |
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