catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN (3))-1,2,3-triazol-1-ido-κ(2) N (1):N (3)]

In the title complex, [Zn(C(10)H(8)N(5))Cl](n), the Zn(II) ion is four-coordinated by one Cl atom and three N atoms from two in situ-generated deprotonated 5-(1-methyl-1H-benzimidazol-2-yl-κN (3))-1,2,3-triazol-1-ide ligands in a slightly distorted tetra­hedral geometry. The Zn(II) ions are bridged...

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Detalles Bibliográficos
Autores principales: Sun, Chen-Guang, Song, Ji-Rong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343902/
https://www.ncbi.nlm.nih.gov/pubmed/22589870
http://dx.doi.org/10.1107/S1600536812012706
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author Sun, Chen-Guang
Song, Ji-Rong
author_facet Sun, Chen-Guang
Song, Ji-Rong
author_sort Sun, Chen-Guang
collection PubMed
description In the title complex, [Zn(C(10)H(8)N(5))Cl](n), the Zn(II) ion is four-coordinated by one Cl atom and three N atoms from two in situ-generated deprotonated 5-(1-methyl-1H-benzimidazol-2-yl-κN (3))-1,2,3-triazol-1-ide ligands in a slightly distorted tetra­hedral geometry. The Zn(II) ions are bridged by the ligands, forming a helical chain along [001]. C—H⋯N and C—H⋯Cl hydrogen bonds and π–π inter­actions between the imidazole rings [centroid–centroid distance = 3.4244 (10) Å] assemble the chains into a three-dimensional supra­molecular network.
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spelling pubmed-33439022012-05-15 catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN (3))-1,2,3-triazol-1-ido-κ(2) N (1):N (3)] Sun, Chen-Guang Song, Ji-Rong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(10)H(8)N(5))Cl](n), the Zn(II) ion is four-coordinated by one Cl atom and three N atoms from two in situ-generated deprotonated 5-(1-methyl-1H-benzimidazol-2-yl-κN (3))-1,2,3-triazol-1-ide ligands in a slightly distorted tetra­hedral geometry. The Zn(II) ions are bridged by the ligands, forming a helical chain along [001]. C—H⋯N and C—H⋯Cl hydrogen bonds and π–π inter­actions between the imidazole rings [centroid–centroid distance = 3.4244 (10) Å] assemble the chains into a three-dimensional supra­molecular network. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343902/ /pubmed/22589870 http://dx.doi.org/10.1107/S1600536812012706 Text en © Sun and Song 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sun, Chen-Guang
Song, Ji-Rong
catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN (3))-1,2,3-triazol-1-ido-κ(2) N (1):N (3)]
title catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN (3))-1,2,3-triazol-1-ido-κ(2) N (1):N (3)]
title_full catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN (3))-1,2,3-triazol-1-ido-κ(2) N (1):N (3)]
title_fullStr catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN (3))-1,2,3-triazol-1-ido-κ(2) N (1):N (3)]
title_full_unstemmed catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN (3))-1,2,3-triazol-1-ido-κ(2) N (1):N (3)]
title_short catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN (3))-1,2,3-triazol-1-ido-κ(2) N (1):N (3)]
title_sort catena-poly[(chloridozinc)-μ-5-(1-methyl-1h-benzimidazol-2-yl-κn (3))-1,2,3-triazol-1-ido-κ(2) n (1):n (3)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343902/
https://www.ncbi.nlm.nih.gov/pubmed/22589870
http://dx.doi.org/10.1107/S1600536812012706
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