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Diaqua­bis­(2-iodo­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)

In the title complex, [Co(C(7)H(4)IO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) cation is located on an inversion center and is coordinated by two monodentate 2-iodo­benzoate (IB) anions, two nicotin­amide (NA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around th...

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Detalles Bibliográficos
Autores principales: Aydın, Ömür, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343903/
https://www.ncbi.nlm.nih.gov/pubmed/22589871
http://dx.doi.org/10.1107/S160053681201330X
Descripción
Sumario:In the title complex, [Co(C(7)H(4)IO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) cation is located on an inversion center and is coordinated by two monodentate 2-iodo­benzoate (IB) anions, two nicotin­amide (NA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around the Co(II) cation form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 22.3 (3)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 84.59 (13)°. Intra­molecular O—H⋯O hydrogen bonding occurs between the carboxyl­ate group and coordinated water mol­ecule. In the crystal, N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular network.