Cargando…

Diaqua­bis­(2-iodo­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)

In the title complex, [Co(C(7)H(4)IO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) cation is located on an inversion center and is coordinated by two monodentate 2-iodo­benzoate (IB) anions, two nicotin­amide (NA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around th...

Descripción completa

Detalles Bibliográficos
Autores principales: Aydın, Ömür, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343903/
https://www.ncbi.nlm.nih.gov/pubmed/22589871
http://dx.doi.org/10.1107/S160053681201330X
_version_ 1782231870722801664
author Aydın, Ömür
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Aydın, Ömür
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Aydın, Ömür
collection PubMed
description In the title complex, [Co(C(7)H(4)IO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) cation is located on an inversion center and is coordinated by two monodentate 2-iodo­benzoate (IB) anions, two nicotin­amide (NA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around the Co(II) cation form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 22.3 (3)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 84.59 (13)°. Intra­molecular O—H⋯O hydrogen bonding occurs between the carboxyl­ate group and coordinated water mol­ecule. In the crystal, N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular network.
format Online
Article
Text
id pubmed-3343903
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33439032012-05-15 Diaqua­bis­(2-iodo­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II) Aydın, Ömür Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(7)H(4)IO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) cation is located on an inversion center and is coordinated by two monodentate 2-iodo­benzoate (IB) anions, two nicotin­amide (NA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around the Co(II) cation form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 22.3 (3)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 84.59 (13)°. Intra­molecular O—H⋯O hydrogen bonding occurs between the carboxyl­ate group and coordinated water mol­ecule. In the crystal, N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular network. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343903/ /pubmed/22589871 http://dx.doi.org/10.1107/S160053681201330X Text en © Aydın et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Aydın, Ömür
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
Diaqua­bis­(2-iodo­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title Diaqua­bis­(2-iodo­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_full Diaqua­bis­(2-iodo­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_fullStr Diaqua­bis­(2-iodo­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_full_unstemmed Diaqua­bis­(2-iodo­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_short Diaqua­bis­(2-iodo­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_sort diaqua­bis­(2-iodo­benzoato-κo)bis­(nicotinamide-κn (1))cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343903/
https://www.ncbi.nlm.nih.gov/pubmed/22589871
http://dx.doi.org/10.1107/S160053681201330X
work_keys_str_mv AT aydınomur diaquabis2iodobenzoatokobisnicotinamidekn1cobaltii
AT caylakdelibasnagihan diaquabis2iodobenzoatokobisnicotinamidekn1cobaltii
AT necefogluhacali diaquabis2iodobenzoatokobisnicotinamidekn1cobaltii
AT hokelektuncer diaquabis2iodobenzoatokobisnicotinamidekn1cobaltii