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catena-Poly[(diaqua­strontium)-bis­{μ-5-[4-(1H-imidazol-1-yl)phen­yl]tetra­zolido}]

In the title complex polymer, [Sr(C(10)H(7)N(6))(2)(H(2)O)(2)](n), the Sr(II) atom lies on an inversion centre and is coordinated by four N atoms from two bidentate bridging trans-related 5-[4-(1H-imidazol-1-yl)phen­yl]tetra­zolide ligands [Sr—N = 2.387 (4) Å for the tetrazolide moiety and Sr—N = 2....

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Detalles Bibliográficos
Autores principales: Tong, Shao-Wei, Li, Shi-Jie, Song, Wen-Dong, Miao, Dong-Liang, Deng, Qi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343904/
https://www.ncbi.nlm.nih.gov/pubmed/22589872
http://dx.doi.org/10.1107/S1600536812013347
Descripción
Sumario:In the title complex polymer, [Sr(C(10)H(7)N(6))(2)(H(2)O)(2)](n), the Sr(II) atom lies on an inversion centre and is coordinated by four N atoms from two bidentate bridging trans-related 5-[4-(1H-imidazol-1-yl)phen­yl]tetra­zolide ligands [Sr—N = 2.387 (4) Å for the tetrazolide moiety and Sr—N = 2.273 (5) Å for the imidazole moiety], and by two O atoms from water mol­ecules [Sr—O = 2.464 (4) Å], giving a distorted octa­hedral coordination. Pairs of ligand bridges link the complex units, forming chains which extend along [111] and are inter-associated through O(water)—H⋯N hydrogen bonds, giving a two-dimensional network structure parallel to (001). Weak π–π stacking inter­actions between the benzene and imidazole rings are also present [minimum ring centroid separation = 3.691 (4) Å].