Cargando…

catena-Poly[(diaqua­strontium)-bis­{μ-5-[4-(1H-imidazol-1-yl)phen­yl]tetra­zolido}]

In the title complex polymer, [Sr(C(10)H(7)N(6))(2)(H(2)O)(2)](n), the Sr(II) atom lies on an inversion centre and is coordinated by four N atoms from two bidentate bridging trans-related 5-[4-(1H-imidazol-1-yl)phen­yl]tetra­zolide ligands [Sr—N = 2.387 (4) Å for the tetrazolide moiety and Sr—N = 2....

Descripción completa

Detalles Bibliográficos
Autores principales: Tong, Shao-Wei, Li, Shi-Jie, Song, Wen-Dong, Miao, Dong-Liang, Deng, Qi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343904/
https://www.ncbi.nlm.nih.gov/pubmed/22589872
http://dx.doi.org/10.1107/S1600536812013347
_version_ 1782231870957682688
author Tong, Shao-Wei
Li, Shi-Jie
Song, Wen-Dong
Miao, Dong-Liang
Deng, Qi
author_facet Tong, Shao-Wei
Li, Shi-Jie
Song, Wen-Dong
Miao, Dong-Liang
Deng, Qi
author_sort Tong, Shao-Wei
collection PubMed
description In the title complex polymer, [Sr(C(10)H(7)N(6))(2)(H(2)O)(2)](n), the Sr(II) atom lies on an inversion centre and is coordinated by four N atoms from two bidentate bridging trans-related 5-[4-(1H-imidazol-1-yl)phen­yl]tetra­zolide ligands [Sr—N = 2.387 (4) Å for the tetrazolide moiety and Sr—N = 2.273 (5) Å for the imidazole moiety], and by two O atoms from water mol­ecules [Sr—O = 2.464 (4) Å], giving a distorted octa­hedral coordination. Pairs of ligand bridges link the complex units, forming chains which extend along [111] and are inter-associated through O(water)—H⋯N hydrogen bonds, giving a two-dimensional network structure parallel to (001). Weak π–π stacking inter­actions between the benzene and imidazole rings are also present [minimum ring centroid separation = 3.691 (4) Å].
format Online
Article
Text
id pubmed-3343904
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33439042012-05-15 catena-Poly[(diaqua­strontium)-bis­{μ-5-[4-(1H-imidazol-1-yl)phen­yl]tetra­zolido}] Tong, Shao-Wei Li, Shi-Jie Song, Wen-Dong Miao, Dong-Liang Deng, Qi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex polymer, [Sr(C(10)H(7)N(6))(2)(H(2)O)(2)](n), the Sr(II) atom lies on an inversion centre and is coordinated by four N atoms from two bidentate bridging trans-related 5-[4-(1H-imidazol-1-yl)phen­yl]tetra­zolide ligands [Sr—N = 2.387 (4) Å for the tetrazolide moiety and Sr—N = 2.273 (5) Å for the imidazole moiety], and by two O atoms from water mol­ecules [Sr—O = 2.464 (4) Å], giving a distorted octa­hedral coordination. Pairs of ligand bridges link the complex units, forming chains which extend along [111] and are inter-associated through O(water)—H⋯N hydrogen bonds, giving a two-dimensional network structure parallel to (001). Weak π–π stacking inter­actions between the benzene and imidazole rings are also present [minimum ring centroid separation = 3.691 (4) Å]. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343904/ /pubmed/22589872 http://dx.doi.org/10.1107/S1600536812013347 Text en © Tong et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tong, Shao-Wei
Li, Shi-Jie
Song, Wen-Dong
Miao, Dong-Liang
Deng, Qi
catena-Poly[(diaqua­strontium)-bis­{μ-5-[4-(1H-imidazol-1-yl)phen­yl]tetra­zolido}]
title catena-Poly[(diaqua­strontium)-bis­{μ-5-[4-(1H-imidazol-1-yl)phen­yl]tetra­zolido}]
title_full catena-Poly[(diaqua­strontium)-bis­{μ-5-[4-(1H-imidazol-1-yl)phen­yl]tetra­zolido}]
title_fullStr catena-Poly[(diaqua­strontium)-bis­{μ-5-[4-(1H-imidazol-1-yl)phen­yl]tetra­zolido}]
title_full_unstemmed catena-Poly[(diaqua­strontium)-bis­{μ-5-[4-(1H-imidazol-1-yl)phen­yl]tetra­zolido}]
title_short catena-Poly[(diaqua­strontium)-bis­{μ-5-[4-(1H-imidazol-1-yl)phen­yl]tetra­zolido}]
title_sort catena-poly[(diaqua­strontium)-bis­{μ-5-[4-(1h-imidazol-1-yl)phen­yl]tetra­zolido}]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343904/
https://www.ncbi.nlm.nih.gov/pubmed/22589872
http://dx.doi.org/10.1107/S1600536812013347
work_keys_str_mv AT tongshaowei catenapolydiaquastrontiumbism541himidazol1ylphenyltetrazolido
AT lishijie catenapolydiaquastrontiumbism541himidazol1ylphenyltetrazolido
AT songwendong catenapolydiaquastrontiumbism541himidazol1ylphenyltetrazolido
AT miaodongliang catenapolydiaquastrontiumbism541himidazol1ylphenyltetrazolido
AT dengqi catenapolydiaquastrontiumbism541himidazol1ylphenyltetrazolido