Dibromidobis(pyrazine-2-carboxamide-κN (4))zinc

The title complex, [ZnBr(2)(C(5)H(5)N(3)O)(2)], shows crystallographic mirror symmetry with the Zn atom and the two bromine ligands located on the mirror plane. The Zn atom is four-coordinated in a distorted tetra­hedral fashion by two N atoms from two pyrazine-2-carboxamide ligands and two Br atoms...

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Detalles Bibliográficos
Autores principales: Shirvan, Sadif A., Haydari Dezfuli, Sara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343906/
https://www.ncbi.nlm.nih.gov/pubmed/22589874
http://dx.doi.org/10.1107/S1600536812013335
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author Shirvan, Sadif A.
Haydari Dezfuli, Sara
author_facet Shirvan, Sadif A.
Haydari Dezfuli, Sara
author_sort Shirvan, Sadif A.
collection PubMed
description The title complex, [ZnBr(2)(C(5)H(5)N(3)O)(2)], shows crystallographic mirror symmetry with the Zn atom and the two bromine ligands located on the mirror plane. The Zn atom is four-coordinated in a distorted tetra­hedral fashion by two N atoms from two pyrazine-2-carboxamide ligands and two Br atoms. Only one of the amino H atoms is involved in an N—H⋯O hydrogen bond. The crystal packing is further stabilized by weak N—H⋯N and C—H⋯O inter­actions.
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spelling pubmed-33439062012-05-15 Dibromidobis(pyrazine-2-carboxamide-κN (4))zinc Shirvan, Sadif A. Haydari Dezfuli, Sara Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [ZnBr(2)(C(5)H(5)N(3)O)(2)], shows crystallographic mirror symmetry with the Zn atom and the two bromine ligands located on the mirror plane. The Zn atom is four-coordinated in a distorted tetra­hedral fashion by two N atoms from two pyrazine-2-carboxamide ligands and two Br atoms. Only one of the amino H atoms is involved in an N—H⋯O hydrogen bond. The crystal packing is further stabilized by weak N—H⋯N and C—H⋯O inter­actions. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343906/ /pubmed/22589874 http://dx.doi.org/10.1107/S1600536812013335 Text en © Shirvan and Haydari Dezfuli 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shirvan, Sadif A.
Haydari Dezfuli, Sara
Dibromidobis(pyrazine-2-carboxamide-κN (4))zinc
title Dibromidobis(pyrazine-2-carboxamide-κN (4))zinc
title_full Dibromidobis(pyrazine-2-carboxamide-κN (4))zinc
title_fullStr Dibromidobis(pyrazine-2-carboxamide-κN (4))zinc
title_full_unstemmed Dibromidobis(pyrazine-2-carboxamide-κN (4))zinc
title_short Dibromidobis(pyrazine-2-carboxamide-κN (4))zinc
title_sort dibromidobis(pyrazine-2-carboxamide-κn (4))zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343906/
https://www.ncbi.nlm.nih.gov/pubmed/22589874
http://dx.doi.org/10.1107/S1600536812013335
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