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4-Meth­oxy­benzoyl-meso-octa­methyl­calix[2]pyrrolidino[2]pyrrole: an acyl chloride derivative of a partially reduced calix[4]pyrrole

In the title compound, C(36)H(50)N(4)O(2), the two pyrrolidine rings have envelope conformations. The conformation of the macrocycle is stabilized by N—H⋯N hydrogen bonds and a C—H⋯N inter­action. The benzoyl ring is inclined to an adjacent pyrrole ring by 6.76 (9)°, with a centroid-to-centroid dist...

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Detalles Bibliográficos
Autores principales: Journot, Guillaume, Neier, Reinhard, Stoeckli-Evans, Helen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343912/
https://www.ncbi.nlm.nih.gov/pubmed/22589993
http://dx.doi.org/10.1107/S1600536812008008
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author Journot, Guillaume
Neier, Reinhard
Stoeckli-Evans, Helen
author_facet Journot, Guillaume
Neier, Reinhard
Stoeckli-Evans, Helen
author_sort Journot, Guillaume
collection PubMed
description In the title compound, C(36)H(50)N(4)O(2), the two pyrrolidine rings have envelope conformations. The conformation of the macrocycle is stabilized by N—H⋯N hydrogen bonds and a C—H⋯N inter­action. The benzoyl ring is inclined to an adjacent pyrrole ring by 6.76 (9)°, with a centroid-to-centroid distance of 3.6285 (10) Å. In the crystal, apart from a C—H⋯O and a C—H⋯π inter­action, mol­ecules are linked via an N—H⋯O hydrogen bond, leading to the formation of helical chains propagating along [010].
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spelling pubmed-33439122012-05-15 4-Meth­oxy­benzoyl-meso-octa­methyl­calix[2]pyrrolidino[2]pyrrole: an acyl chloride derivative of a partially reduced calix[4]pyrrole Journot, Guillaume Neier, Reinhard Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(36)H(50)N(4)O(2), the two pyrrolidine rings have envelope conformations. The conformation of the macrocycle is stabilized by N—H⋯N hydrogen bonds and a C—H⋯N inter­action. The benzoyl ring is inclined to an adjacent pyrrole ring by 6.76 (9)°, with a centroid-to-centroid distance of 3.6285 (10) Å. In the crystal, apart from a C—H⋯O and a C—H⋯π inter­action, mol­ecules are linked via an N—H⋯O hydrogen bond, leading to the formation of helical chains propagating along [010]. International Union of Crystallography 2012-03-07 /pmc/articles/PMC3343912/ /pubmed/22589993 http://dx.doi.org/10.1107/S1600536812008008 Text en © Journot et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Journot, Guillaume
Neier, Reinhard
Stoeckli-Evans, Helen
4-Meth­oxy­benzoyl-meso-octa­methyl­calix[2]pyrrolidino[2]pyrrole: an acyl chloride derivative of a partially reduced calix[4]pyrrole
title 4-Meth­oxy­benzoyl-meso-octa­methyl­calix[2]pyrrolidino[2]pyrrole: an acyl chloride derivative of a partially reduced calix[4]pyrrole
title_full 4-Meth­oxy­benzoyl-meso-octa­methyl­calix[2]pyrrolidino[2]pyrrole: an acyl chloride derivative of a partially reduced calix[4]pyrrole
title_fullStr 4-Meth­oxy­benzoyl-meso-octa­methyl­calix[2]pyrrolidino[2]pyrrole: an acyl chloride derivative of a partially reduced calix[4]pyrrole
title_full_unstemmed 4-Meth­oxy­benzoyl-meso-octa­methyl­calix[2]pyrrolidino[2]pyrrole: an acyl chloride derivative of a partially reduced calix[4]pyrrole
title_short 4-Meth­oxy­benzoyl-meso-octa­methyl­calix[2]pyrrolidino[2]pyrrole: an acyl chloride derivative of a partially reduced calix[4]pyrrole
title_sort 4-meth­oxy­benzoyl-meso-octa­methyl­calix[2]pyrrolidino[2]pyrrole: an acyl chloride derivative of a partially reduced calix[4]pyrrole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343912/
https://www.ncbi.nlm.nih.gov/pubmed/22589993
http://dx.doi.org/10.1107/S1600536812008008
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