Diisopropyl {[(R)-2-(2-amino-6-chloro-9H-purin-9-yl)-1-methyl­eth­oxy]meth­yl}­phospho­nate

In the title compound, C(15)H(25)ClN(5)O(4)P, the r.m.s. deviation for the purine ring system is 0.0165 Å. The coordination about the P atom is a distorted tetrahedron [O=P—O angles = 116.70 (6) and 109.87 (6)°]. In the crystal, molecules are linked by N—H⋯O hydrogen bonds, generating a three-dimens...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhao, Guobao, He, Xinhua, Zhong, Bohua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343918/
https://www.ncbi.nlm.nih.gov/pubmed/22589999
http://dx.doi.org/10.1107/S1600536812006757
_version_ 1782231874108653568
author Zhao, Guobao
He, Xinhua
Zhong, Bohua
author_facet Zhao, Guobao
He, Xinhua
Zhong, Bohua
author_sort Zhao, Guobao
collection PubMed
description In the title compound, C(15)H(25)ClN(5)O(4)P, the r.m.s. deviation for the purine ring system is 0.0165 Å. The coordination about the P atom is a distorted tetrahedron [O=P—O angles = 116.70 (6) and 109.87 (6)°]. In the crystal, molecules are linked by N—H⋯O hydrogen bonds, generating a three-dimensional network.
format Online
Article
Text
id pubmed-3343918
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33439182012-05-15 Diisopropyl {[(R)-2-(2-amino-6-chloro-9H-purin-9-yl)-1-methyl­eth­oxy]meth­yl}­phospho­nate Zhao, Guobao He, Xinhua Zhong, Bohua Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(25)ClN(5)O(4)P, the r.m.s. deviation for the purine ring system is 0.0165 Å. The coordination about the P atom is a distorted tetrahedron [O=P—O angles = 116.70 (6) and 109.87 (6)°]. In the crystal, molecules are linked by N—H⋯O hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2012-03-03 /pmc/articles/PMC3343918/ /pubmed/22589999 http://dx.doi.org/10.1107/S1600536812006757 Text en © Zhao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhao, Guobao
He, Xinhua
Zhong, Bohua
Diisopropyl {[(R)-2-(2-amino-6-chloro-9H-purin-9-yl)-1-methyl­eth­oxy]meth­yl}­phospho­nate
title Diisopropyl {[(R)-2-(2-amino-6-chloro-9H-purin-9-yl)-1-methyl­eth­oxy]meth­yl}­phospho­nate
title_full Diisopropyl {[(R)-2-(2-amino-6-chloro-9H-purin-9-yl)-1-methyl­eth­oxy]meth­yl}­phospho­nate
title_fullStr Diisopropyl {[(R)-2-(2-amino-6-chloro-9H-purin-9-yl)-1-methyl­eth­oxy]meth­yl}­phospho­nate
title_full_unstemmed Diisopropyl {[(R)-2-(2-amino-6-chloro-9H-purin-9-yl)-1-methyl­eth­oxy]meth­yl}­phospho­nate
title_short Diisopropyl {[(R)-2-(2-amino-6-chloro-9H-purin-9-yl)-1-methyl­eth­oxy]meth­yl}­phospho­nate
title_sort diisopropyl {[(r)-2-(2-amino-6-chloro-9h-purin-9-yl)-1-methyl­eth­oxy]meth­yl}­phospho­nate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343918/
https://www.ncbi.nlm.nih.gov/pubmed/22589999
http://dx.doi.org/10.1107/S1600536812006757
work_keys_str_mv AT zhaoguobao diisopropylr22amino6chloro9hpurin9yl1methylethoxymethylphosphonate
AT hexinhua diisopropylr22amino6chloro9hpurin9yl1methylethoxymethylphosphonate
AT zhongbohua diisopropylr22amino6chloro9hpurin9yl1methylethoxymethylphosphonate

Ejemplares similares