2-Methyl­sulfanyl-5,6-dihydro-2H-1,3-dithiolo[4,5-b][1,4]dioxin-2-ium tetra­fluoro­borate

The title compound, C(6)H(7)O(2)S(3) (+)·BF(4) (−), consists of a planar 2-thioxo-1,3-dithiol-4,5-yl unit [maximum deviation from the ring plane = 0.020 (3) Å], with an ethyl­enedi­oxy group fused at the 4,5-positions; the ethyl­enedi­oxy C atoms are disordered over two positions with site-occupancy...

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Detalles Bibliográficos
Autores principales: Zhou, Guoquan, Chen, Xinzhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343930/
https://www.ncbi.nlm.nih.gov/pubmed/22590011
http://dx.doi.org/10.1107/S1600536812005326
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author Zhou, Guoquan
Chen, Xinzhi
author_facet Zhou, Guoquan
Chen, Xinzhi
author_sort Zhou, Guoquan
collection PubMed
description The title compound, C(6)H(7)O(2)S(3) (+)·BF(4) (−), consists of a planar 2-thioxo-1,3-dithiol-4,5-yl unit [maximum deviation from the ring plane = 0.020 (3) Å], with an ethyl­enedi­oxy group fused at the 4,5-positions; the ethyl­enedi­oxy C atoms are disordered over two positions with site-occupancy factors of 0.5. The 1,4-dioxine ring has a twist-chair conformation. Weak cation–anion S⋯F inter­actions [3.022 (4)–3.095 (4) Å] and an S⋯O [3.247 (4) Å] inter­action are present.
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spelling pubmed-33439302012-05-15 2-Methyl­sulfanyl-5,6-dihydro-2H-1,3-dithiolo[4,5-b][1,4]dioxin-2-ium tetra­fluoro­borate Zhou, Guoquan Chen, Xinzhi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(6)H(7)O(2)S(3) (+)·BF(4) (−), consists of a planar 2-thioxo-1,3-dithiol-4,5-yl unit [maximum deviation from the ring plane = 0.020 (3) Å], with an ethyl­enedi­oxy group fused at the 4,5-positions; the ethyl­enedi­oxy C atoms are disordered over two positions with site-occupancy factors of 0.5. The 1,4-dioxine ring has a twist-chair conformation. Weak cation–anion S⋯F inter­actions [3.022 (4)–3.095 (4) Å] and an S⋯O [3.247 (4) Å] inter­action are present. International Union of Crystallography 2012-03-03 /pmc/articles/PMC3343930/ /pubmed/22590011 http://dx.doi.org/10.1107/S1600536812005326 Text en © Zhou and Chen 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhou, Guoquan
Chen, Xinzhi
2-Methyl­sulfanyl-5,6-dihydro-2H-1,3-dithiolo[4,5-b][1,4]dioxin-2-ium tetra­fluoro­borate
title 2-Methyl­sulfanyl-5,6-dihydro-2H-1,3-dithiolo[4,5-b][1,4]dioxin-2-ium tetra­fluoro­borate
title_full 2-Methyl­sulfanyl-5,6-dihydro-2H-1,3-dithiolo[4,5-b][1,4]dioxin-2-ium tetra­fluoro­borate
title_fullStr 2-Methyl­sulfanyl-5,6-dihydro-2H-1,3-dithiolo[4,5-b][1,4]dioxin-2-ium tetra­fluoro­borate
title_full_unstemmed 2-Methyl­sulfanyl-5,6-dihydro-2H-1,3-dithiolo[4,5-b][1,4]dioxin-2-ium tetra­fluoro­borate
title_short 2-Methyl­sulfanyl-5,6-dihydro-2H-1,3-dithiolo[4,5-b][1,4]dioxin-2-ium tetra­fluoro­borate
title_sort 2-methyl­sulfanyl-5,6-dihydro-2h-1,3-dithiolo[4,5-b][1,4]dioxin-2-ium tetra­fluoro­borate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343930/
https://www.ncbi.nlm.nih.gov/pubmed/22590011
http://dx.doi.org/10.1107/S1600536812005326
work_keys_str_mv AT zhouguoquan 2methylsulfanyl56dihydro2h13dithiolo45b14dioxin2iumtetrafluoroborate
AT chenxinzhi 2methylsulfanyl56dihydro2h13dithiolo45b14dioxin2iumtetrafluoroborate

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