N,N′-[1,3-Phenyl­enebis(methyl­ene)]di-p-toluenesulfonamide

In the title compound, C(22)H(24)N(2)O(4)S(2), the dihedral angles between the central benzene ring and the pendant rings are 66.96 (13) and 69.37 (13)°. The torsion angles for the C—N—S—C fragments are −68.5 (3) and −72.6 (3)°. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds to genera...

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Detalles Bibliográficos
Autores principales: Ejaz, Khan, Islam Ullah, Harrison, William T. A., Anjum, Rukhsana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343931/
https://www.ncbi.nlm.nih.gov/pubmed/22590012
http://dx.doi.org/10.1107/S1600536812007222
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author Ejaz,
Khan, Islam Ullah
Harrison, William T. A.
Anjum, Rukhsana
author_facet Ejaz,
Khan, Islam Ullah
Harrison, William T. A.
Anjum, Rukhsana
author_sort Ejaz,
collection PubMed
description In the title compound, C(22)H(24)N(2)O(4)S(2), the dihedral angles between the central benzene ring and the pendant rings are 66.96 (13) and 69.37 (13)°. The torsion angles for the C—N—S—C fragments are −68.5 (3) and −72.6 (3)°. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds to generate infinite (001) sheets containing R (4) (4)(28) loops. A weak aromatic π–π stacking contact between one of the terminal benzene rings and its inversion-related partner is also observed [centroid-to-centroid separation = 3.796 (2) Å and slippage = 1.581 Å], as are two possible C—H⋯π contacts.
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spelling pubmed-33439312012-05-15 N,N′-[1,3-Phenyl­enebis(methyl­ene)]di-p-toluenesulfonamide Ejaz, Khan, Islam Ullah Harrison, William T. A. Anjum, Rukhsana Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(24)N(2)O(4)S(2), the dihedral angles between the central benzene ring and the pendant rings are 66.96 (13) and 69.37 (13)°. The torsion angles for the C—N—S—C fragments are −68.5 (3) and −72.6 (3)°. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds to generate infinite (001) sheets containing R (4) (4)(28) loops. A weak aromatic π–π stacking contact between one of the terminal benzene rings and its inversion-related partner is also observed [centroid-to-centroid separation = 3.796 (2) Å and slippage = 1.581 Å], as are two possible C—H⋯π contacts. International Union of Crystallography 2012-03-03 /pmc/articles/PMC3343931/ /pubmed/22590012 http://dx.doi.org/10.1107/S1600536812007222 Text en © Ejaz et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ejaz,
Khan, Islam Ullah
Harrison, William T. A.
Anjum, Rukhsana
N,N′-[1,3-Phenyl­enebis(methyl­ene)]di-p-toluenesulfonamide
title N,N′-[1,3-Phenyl­enebis(methyl­ene)]di-p-toluenesulfonamide
title_full N,N′-[1,3-Phenyl­enebis(methyl­ene)]di-p-toluenesulfonamide
title_fullStr N,N′-[1,3-Phenyl­enebis(methyl­ene)]di-p-toluenesulfonamide
title_full_unstemmed N,N′-[1,3-Phenyl­enebis(methyl­ene)]di-p-toluenesulfonamide
title_short N,N′-[1,3-Phenyl­enebis(methyl­ene)]di-p-toluenesulfonamide
title_sort n,n′-[1,3-phenyl­enebis(methyl­ene)]di-p-toluenesulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343931/
https://www.ncbi.nlm.nih.gov/pubmed/22590012
http://dx.doi.org/10.1107/S1600536812007222
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AT anjumrukhsana nn13phenylenebismethylenediptoluenesulfonamide

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