(E)-N′-(5-Chloro-2-hy­droxy­benzyl­idene)-2,4-dihy­droxybenzohydrazide methanol monosolvate

In the title compound, C(14)H(11)ClN(2)O(4)·CH(3)OH, the mol­ecule adopts an E conformation about the C=N bond. The compound is in the enamine–keto form. The two terminal benzene rings make a dihedral angle of 10.53 (9)°. Intra-mol­ecular O—H⋯O and O—H⋯N hydrogen bonding stabilizes the mol­ecular st...

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Detalles Bibliográficos
Autor principal: Li, Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343942/
https://www.ncbi.nlm.nih.gov/pubmed/22590023
http://dx.doi.org/10.1107/S1600536812009178
Descripción
Sumario:In the title compound, C(14)H(11)ClN(2)O(4)·CH(3)OH, the mol­ecule adopts an E conformation about the C=N bond. The compound is in the enamine–keto form. The two terminal benzene rings make a dihedral angle of 10.53 (9)°. Intra-mol­ecular O—H⋯O and O—H⋯N hydrogen bonding stabilizes the mol­ecular structure. In the crystal, O—H⋯O hydrogen bonds link the mol­ecules, forming chains running along the b axis.

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