(E)-N′-(5-Chloro-2-hy­droxy­benzyl­idene)-2,4-dihy­droxybenzohydrazide methanol monosolvate

In the title compound, C(14)H(11)ClN(2)O(4)·CH(3)OH, the mol­ecule adopts an E conformation about the C=N bond. The compound is in the enamine–keto form. The two terminal benzene rings make a dihedral angle of 10.53 (9)°. Intra-mol­ecular O—H⋯O and O—H⋯N hydrogen bonding stabilizes the mol­ecular st...

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Detalles Bibliográficos
Autor principal: Li, Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343942/
https://www.ncbi.nlm.nih.gov/pubmed/22590023
http://dx.doi.org/10.1107/S1600536812009178
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author Li, Kun
author_facet Li, Kun
author_sort Li, Kun
collection PubMed
description In the title compound, C(14)H(11)ClN(2)O(4)·CH(3)OH, the mol­ecule adopts an E conformation about the C=N bond. The compound is in the enamine–keto form. The two terminal benzene rings make a dihedral angle of 10.53 (9)°. Intra-mol­ecular O—H⋯O and O—H⋯N hydrogen bonding stabilizes the mol­ecular structure. In the crystal, O—H⋯O hydrogen bonds link the mol­ecules, forming chains running along the b axis.
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spelling pubmed-33439422012-05-15 (E)-N′-(5-Chloro-2-hy­droxy­benzyl­idene)-2,4-dihy­droxybenzohydrazide methanol monosolvate Li, Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(11)ClN(2)O(4)·CH(3)OH, the mol­ecule adopts an E conformation about the C=N bond. The compound is in the enamine–keto form. The two terminal benzene rings make a dihedral angle of 10.53 (9)°. Intra-mol­ecular O—H⋯O and O—H⋯N hydrogen bonding stabilizes the mol­ecular structure. In the crystal, O—H⋯O hydrogen bonds link the mol­ecules, forming chains running along the b axis. International Union of Crystallography 2012-03-07 /pmc/articles/PMC3343942/ /pubmed/22590023 http://dx.doi.org/10.1107/S1600536812009178 Text en © Kun Li 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Kun
(E)-N′-(5-Chloro-2-hy­droxy­benzyl­idene)-2,4-dihy­droxybenzohydrazide methanol monosolvate
title (E)-N′-(5-Chloro-2-hy­droxy­benzyl­idene)-2,4-dihy­droxybenzohydrazide methanol monosolvate
title_full (E)-N′-(5-Chloro-2-hy­droxy­benzyl­idene)-2,4-dihy­droxybenzohydrazide methanol monosolvate
title_fullStr (E)-N′-(5-Chloro-2-hy­droxy­benzyl­idene)-2,4-dihy­droxybenzohydrazide methanol monosolvate
title_full_unstemmed (E)-N′-(5-Chloro-2-hy­droxy­benzyl­idene)-2,4-dihy­droxybenzohydrazide methanol monosolvate
title_short (E)-N′-(5-Chloro-2-hy­droxy­benzyl­idene)-2,4-dihy­droxybenzohydrazide methanol monosolvate
title_sort (e)-n′-(5-chloro-2-hy­droxy­benzyl­idene)-2,4-dihy­droxybenzohydrazide methanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343942/
https://www.ncbi.nlm.nih.gov/pubmed/22590023
http://dx.doi.org/10.1107/S1600536812009178
work_keys_str_mv AT likun en5chloro2hydroxybenzylidene24dihydroxybenzohydrazidemethanolmonosolvate

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