Cargando…
3-[Hydroxy(3-methoxyphenyl)methylidene]-2-(2-oxo-2-phenylethyl)-3,4-dihydro-2H-1λ(6),2-benzothiazine-1,1,4-trione
In the title molecule, C(24)H(19)NO(6)S, the heterocyclic thiazine ring adopts a half-chair conformation with the S and N atoms displaced by 0.180 (5) and 0.497 (5) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The benzene rings of the benzothiazine unit...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343951/ https://www.ncbi.nlm.nih.gov/pubmed/22590032 http://dx.doi.org/10.1107/S1600536812009002 |
_version_ | 1782231881512648704 |
---|---|
author | Siddiqui, Hamid Latif Ahmad, Matloob Gul, Salman Siddiqui, Waseeq Ahmad Parvez, Masood |
author_facet | Siddiqui, Hamid Latif Ahmad, Matloob Gul, Salman Siddiqui, Waseeq Ahmad Parvez, Masood |
author_sort | Siddiqui, Hamid Latif |
collection | PubMed |
description | In the title molecule, C(24)H(19)NO(6)S, the heterocyclic thiazine ring adopts a half-chair conformation with the S and N atoms displaced by 0.180 (5) and 0.497 (5) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The benzene rings of the benzothiazine unit and the methoxyphenyl group are almost coplanar, with the dihedral angle between the mean planes of these rings being 5.9 (2)°, while the benzene ring of the 2-oxo-2-phenylethyl group is inclined at 79.68 (11) and 81.01 (10)°, respectively, to these rings. The molecular structure is consolidated by intramolecular O—H⋯O and C—H⋯N interactions, and the crystal packing is stabilized by weak C—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3343951 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33439512012-05-15 3-[Hydroxy(3-methoxyphenyl)methylidene]-2-(2-oxo-2-phenylethyl)-3,4-dihydro-2H-1λ(6),2-benzothiazine-1,1,4-trione Siddiqui, Hamid Latif Ahmad, Matloob Gul, Salman Siddiqui, Waseeq Ahmad Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(24)H(19)NO(6)S, the heterocyclic thiazine ring adopts a half-chair conformation with the S and N atoms displaced by 0.180 (5) and 0.497 (5) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The benzene rings of the benzothiazine unit and the methoxyphenyl group are almost coplanar, with the dihedral angle between the mean planes of these rings being 5.9 (2)°, while the benzene ring of the 2-oxo-2-phenylethyl group is inclined at 79.68 (11) and 81.01 (10)°, respectively, to these rings. The molecular structure is consolidated by intramolecular O—H⋯O and C—H⋯N interactions, and the crystal packing is stabilized by weak C—H⋯O hydrogen bonds. International Union of Crystallography 2012-03-07 /pmc/articles/PMC3343951/ /pubmed/22590032 http://dx.doi.org/10.1107/S1600536812009002 Text en © Siddiqui et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Siddiqui, Hamid Latif Ahmad, Matloob Gul, Salman Siddiqui, Waseeq Ahmad Parvez, Masood 3-[Hydroxy(3-methoxyphenyl)methylidene]-2-(2-oxo-2-phenylethyl)-3,4-dihydro-2H-1λ(6),2-benzothiazine-1,1,4-trione |
title | 3-[Hydroxy(3-methoxyphenyl)methylidene]-2-(2-oxo-2-phenylethyl)-3,4-dihydro-2H-1λ(6),2-benzothiazine-1,1,4-trione |
title_full | 3-[Hydroxy(3-methoxyphenyl)methylidene]-2-(2-oxo-2-phenylethyl)-3,4-dihydro-2H-1λ(6),2-benzothiazine-1,1,4-trione |
title_fullStr | 3-[Hydroxy(3-methoxyphenyl)methylidene]-2-(2-oxo-2-phenylethyl)-3,4-dihydro-2H-1λ(6),2-benzothiazine-1,1,4-trione |
title_full_unstemmed | 3-[Hydroxy(3-methoxyphenyl)methylidene]-2-(2-oxo-2-phenylethyl)-3,4-dihydro-2H-1λ(6),2-benzothiazine-1,1,4-trione |
title_short | 3-[Hydroxy(3-methoxyphenyl)methylidene]-2-(2-oxo-2-phenylethyl)-3,4-dihydro-2H-1λ(6),2-benzothiazine-1,1,4-trione |
title_sort | 3-[hydroxy(3-methoxyphenyl)methylidene]-2-(2-oxo-2-phenylethyl)-3,4-dihydro-2h-1λ(6),2-benzothiazine-1,1,4-trione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343951/ https://www.ncbi.nlm.nih.gov/pubmed/22590032 http://dx.doi.org/10.1107/S1600536812009002 |
work_keys_str_mv | AT siddiquihamidlatif 3hydroxy3methoxyphenylmethylidene22oxo2phenylethyl34dihydro2h1l62benzothiazine114trione AT ahmadmatloob 3hydroxy3methoxyphenylmethylidene22oxo2phenylethyl34dihydro2h1l62benzothiazine114trione AT gulsalman 3hydroxy3methoxyphenylmethylidene22oxo2phenylethyl34dihydro2h1l62benzothiazine114trione AT siddiquiwaseeqahmad 3hydroxy3methoxyphenylmethylidene22oxo2phenylethyl34dihydro2h1l62benzothiazine114trione AT parvezmasood 3hydroxy3methoxyphenylmethylidene22oxo2phenylethyl34dihydro2h1l62benzothiazine114trione |