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3-[Hy­droxy(3-meth­oxy­phen­yl)methyl­idene]-2-(2-oxo-2-phenyl­eth­yl)-3,4-dihydro-2H-1λ(6),2-benzothia­zine-1,1,4-trione

In the title mol­ecule, C(24)H(19)NO(6)S, the heterocyclic thia­zine ring adopts a half-chair conformation with the S and N atoms displaced by 0.180 (5) and 0.497 (5) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The benzene rings of the benzothia­zine unit...

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Autores principales: Siddiqui, Hamid Latif, Ahmad, Matloob, Gul, Salman, Siddiqui, Waseeq Ahmad, Parvez, Masood
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343951/
https://www.ncbi.nlm.nih.gov/pubmed/22590032
http://dx.doi.org/10.1107/S1600536812009002
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author Siddiqui, Hamid Latif
Ahmad, Matloob
Gul, Salman
Siddiqui, Waseeq Ahmad
Parvez, Masood
author_facet Siddiqui, Hamid Latif
Ahmad, Matloob
Gul, Salman
Siddiqui, Waseeq Ahmad
Parvez, Masood
author_sort Siddiqui, Hamid Latif
collection PubMed
description In the title mol­ecule, C(24)H(19)NO(6)S, the heterocyclic thia­zine ring adopts a half-chair conformation with the S and N atoms displaced by 0.180 (5) and 0.497 (5) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The benzene rings of the benzothia­zine unit and the meth­oxy­phenyl group are almost coplanar, with the dihedral angle between the mean planes of these rings being 5.9 (2)°, while the benzene ring of the 2-oxo-2-phenyl­ethyl group is inclined at 79.68 (11) and 81.01 (10)°, respectively, to these rings. The mol­ecular structure is consolidated by intra­molecular O—H⋯O and C—H⋯N inter­actions, and the crystal packing is stabilized by weak C—H⋯O hydrogen bonds.
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spelling pubmed-33439512012-05-15 3-[Hy­droxy(3-meth­oxy­phen­yl)methyl­idene]-2-(2-oxo-2-phenyl­eth­yl)-3,4-dihydro-2H-1λ(6),2-benzothia­zine-1,1,4-trione Siddiqui, Hamid Latif Ahmad, Matloob Gul, Salman Siddiqui, Waseeq Ahmad Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(24)H(19)NO(6)S, the heterocyclic thia­zine ring adopts a half-chair conformation with the S and N atoms displaced by 0.180 (5) and 0.497 (5) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The benzene rings of the benzothia­zine unit and the meth­oxy­phenyl group are almost coplanar, with the dihedral angle between the mean planes of these rings being 5.9 (2)°, while the benzene ring of the 2-oxo-2-phenyl­ethyl group is inclined at 79.68 (11) and 81.01 (10)°, respectively, to these rings. The mol­ecular structure is consolidated by intra­molecular O—H⋯O and C—H⋯N inter­actions, and the crystal packing is stabilized by weak C—H⋯O hydrogen bonds. International Union of Crystallography 2012-03-07 /pmc/articles/PMC3343951/ /pubmed/22590032 http://dx.doi.org/10.1107/S1600536812009002 Text en © Siddiqui et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Siddiqui, Hamid Latif
Ahmad, Matloob
Gul, Salman
Siddiqui, Waseeq Ahmad
Parvez, Masood
3-[Hy­droxy(3-meth­oxy­phen­yl)methyl­idene]-2-(2-oxo-2-phenyl­eth­yl)-3,4-dihydro-2H-1λ(6),2-benzothia­zine-1,1,4-trione
title 3-[Hy­droxy(3-meth­oxy­phen­yl)methyl­idene]-2-(2-oxo-2-phenyl­eth­yl)-3,4-dihydro-2H-1λ(6),2-benzothia­zine-1,1,4-trione
title_full 3-[Hy­droxy(3-meth­oxy­phen­yl)methyl­idene]-2-(2-oxo-2-phenyl­eth­yl)-3,4-dihydro-2H-1λ(6),2-benzothia­zine-1,1,4-trione
title_fullStr 3-[Hy­droxy(3-meth­oxy­phen­yl)methyl­idene]-2-(2-oxo-2-phenyl­eth­yl)-3,4-dihydro-2H-1λ(6),2-benzothia­zine-1,1,4-trione
title_full_unstemmed 3-[Hy­droxy(3-meth­oxy­phen­yl)methyl­idene]-2-(2-oxo-2-phenyl­eth­yl)-3,4-dihydro-2H-1λ(6),2-benzothia­zine-1,1,4-trione
title_short 3-[Hy­droxy(3-meth­oxy­phen­yl)methyl­idene]-2-(2-oxo-2-phenyl­eth­yl)-3,4-dihydro-2H-1λ(6),2-benzothia­zine-1,1,4-trione
title_sort 3-[hy­droxy(3-meth­oxy­phen­yl)methyl­idene]-2-(2-oxo-2-phenyl­eth­yl)-3,4-dihydro-2h-1λ(6),2-benzothia­zine-1,1,4-trione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343951/
https://www.ncbi.nlm.nih.gov/pubmed/22590032
http://dx.doi.org/10.1107/S1600536812009002
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