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2-[2-(3-Chlorophenyl)-2-oxoethyl]-4-hydroxy-3-(3-methoxybenzoyl)-2H-1λ(6),2-benzothiazine-1,1-dione
In the title molecule, C(24)H(18)ClNO(6)S, the heterocyclic thiazine ring adopts a half chair conformation with the S and N atoms displaced by 0.318 (3) and 0.387 (3) Å, respectively, on the opposite sides from the mean plane formed by the remaining ring atoms. The benzene rings of the benzothiaz...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343952/ https://www.ncbi.nlm.nih.gov/pubmed/22590033 http://dx.doi.org/10.1107/S1600536812009014 |
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author | Siddiqui, Hamid Latif Ahmad, Matloob Gul, Salman Siddiqui, Waseeq Ahmad Parvez, Masood |
author_facet | Siddiqui, Hamid Latif Ahmad, Matloob Gul, Salman Siddiqui, Waseeq Ahmad Parvez, Masood |
author_sort | Siddiqui, Hamid Latif |
collection | PubMed |
description | In the title molecule, C(24)H(18)ClNO(6)S, the heterocyclic thiazine ring adopts a half chair conformation with the S and N atoms displaced by 0.318 (3) and 0.387 (3) Å, respectively, on the opposite sides from the mean plane formed by the remaining ring atoms. The benzene rings of the benzothiazin unit and methoxybenzoyl group are more or less coplanar, the dihedral angle between the mean planes of these rings being 12.37 (10)° while the chlorophenyl ring is inclined at 81.87 (4) and 73.30 (5)°, respectively, to these rings. The molecular structure is consolidated by intramolecular O—H⋯O and C—H⋯N interactions and the crystal packing is stabilized by weak intermolecular C—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3343952 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33439522012-05-15 2-[2-(3-Chlorophenyl)-2-oxoethyl]-4-hydroxy-3-(3-methoxybenzoyl)-2H-1λ(6),2-benzothiazine-1,1-dione Siddiqui, Hamid Latif Ahmad, Matloob Gul, Salman Siddiqui, Waseeq Ahmad Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(24)H(18)ClNO(6)S, the heterocyclic thiazine ring adopts a half chair conformation with the S and N atoms displaced by 0.318 (3) and 0.387 (3) Å, respectively, on the opposite sides from the mean plane formed by the remaining ring atoms. The benzene rings of the benzothiazin unit and methoxybenzoyl group are more or less coplanar, the dihedral angle between the mean planes of these rings being 12.37 (10)° while the chlorophenyl ring is inclined at 81.87 (4) and 73.30 (5)°, respectively, to these rings. The molecular structure is consolidated by intramolecular O—H⋯O and C—H⋯N interactions and the crystal packing is stabilized by weak intermolecular C—H⋯O hydrogen bonds. International Union of Crystallography 2012-03-07 /pmc/articles/PMC3343952/ /pubmed/22590033 http://dx.doi.org/10.1107/S1600536812009014 Text en © Siddiqui et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Siddiqui, Hamid Latif Ahmad, Matloob Gul, Salman Siddiqui, Waseeq Ahmad Parvez, Masood 2-[2-(3-Chlorophenyl)-2-oxoethyl]-4-hydroxy-3-(3-methoxybenzoyl)-2H-1λ(6),2-benzothiazine-1,1-dione |
title | 2-[2-(3-Chlorophenyl)-2-oxoethyl]-4-hydroxy-3-(3-methoxybenzoyl)-2H-1λ(6),2-benzothiazine-1,1-dione |
title_full | 2-[2-(3-Chlorophenyl)-2-oxoethyl]-4-hydroxy-3-(3-methoxybenzoyl)-2H-1λ(6),2-benzothiazine-1,1-dione |
title_fullStr | 2-[2-(3-Chlorophenyl)-2-oxoethyl]-4-hydroxy-3-(3-methoxybenzoyl)-2H-1λ(6),2-benzothiazine-1,1-dione |
title_full_unstemmed | 2-[2-(3-Chlorophenyl)-2-oxoethyl]-4-hydroxy-3-(3-methoxybenzoyl)-2H-1λ(6),2-benzothiazine-1,1-dione |
title_short | 2-[2-(3-Chlorophenyl)-2-oxoethyl]-4-hydroxy-3-(3-methoxybenzoyl)-2H-1λ(6),2-benzothiazine-1,1-dione |
title_sort | 2-[2-(3-chlorophenyl)-2-oxoethyl]-4-hydroxy-3-(3-methoxybenzoyl)-2h-1λ(6),2-benzothiazine-1,1-dione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343952/ https://www.ncbi.nlm.nih.gov/pubmed/22590033 http://dx.doi.org/10.1107/S1600536812009014 |
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