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2-[2-(3-Chloro­phen­yl)-2-oxoeth­yl]-4-hy­droxy-3-(3-meth­oxy­benzo­yl)-2H-1λ(6),2-benzothia­zine-1,1-dione

In the title mol­ecule, C(24)H(18)ClNO(6)S, the heterocyclic thia­zine ring adopts a half chair conformation with the S and N atoms displaced by 0.318 (3) and 0.387 (3) Å, respectively, on the opposite sides from the mean plane formed by the remaining ring atoms. The benzene rings of the benzothia­z...

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Autores principales: Siddiqui, Hamid Latif, Ahmad, Matloob, Gul, Salman, Siddiqui, Waseeq Ahmad, Parvez, Masood
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343952/
https://www.ncbi.nlm.nih.gov/pubmed/22590033
http://dx.doi.org/10.1107/S1600536812009014
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author Siddiqui, Hamid Latif
Ahmad, Matloob
Gul, Salman
Siddiqui, Waseeq Ahmad
Parvez, Masood
author_facet Siddiqui, Hamid Latif
Ahmad, Matloob
Gul, Salman
Siddiqui, Waseeq Ahmad
Parvez, Masood
author_sort Siddiqui, Hamid Latif
collection PubMed
description In the title mol­ecule, C(24)H(18)ClNO(6)S, the heterocyclic thia­zine ring adopts a half chair conformation with the S and N atoms displaced by 0.318 (3) and 0.387 (3) Å, respectively, on the opposite sides from the mean plane formed by the remaining ring atoms. The benzene rings of the benzothia­zin unit and meth­oxy­benzoyl group are more or less coplanar, the dihedral angle between the mean planes of these rings being 12.37 (10)° while the chloro­phenyl ring is inclined at 81.87 (4) and 73.30 (5)°, respectively, to these rings. The mol­ecular structure is consolidated by intra­molecular O—H⋯O and C—H⋯N inter­actions and the crystal packing is stabilized by weak inter­molecular C—H⋯O hydrogen bonds.
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spelling pubmed-33439522012-05-15 2-[2-(3-Chloro­phen­yl)-2-oxoeth­yl]-4-hy­droxy-3-(3-meth­oxy­benzo­yl)-2H-1λ(6),2-benzothia­zine-1,1-dione Siddiqui, Hamid Latif Ahmad, Matloob Gul, Salman Siddiqui, Waseeq Ahmad Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(24)H(18)ClNO(6)S, the heterocyclic thia­zine ring adopts a half chair conformation with the S and N atoms displaced by 0.318 (3) and 0.387 (3) Å, respectively, on the opposite sides from the mean plane formed by the remaining ring atoms. The benzene rings of the benzothia­zin unit and meth­oxy­benzoyl group are more or less coplanar, the dihedral angle between the mean planes of these rings being 12.37 (10)° while the chloro­phenyl ring is inclined at 81.87 (4) and 73.30 (5)°, respectively, to these rings. The mol­ecular structure is consolidated by intra­molecular O—H⋯O and C—H⋯N inter­actions and the crystal packing is stabilized by weak inter­molecular C—H⋯O hydrogen bonds. International Union of Crystallography 2012-03-07 /pmc/articles/PMC3343952/ /pubmed/22590033 http://dx.doi.org/10.1107/S1600536812009014 Text en © Siddiqui et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Siddiqui, Hamid Latif
Ahmad, Matloob
Gul, Salman
Siddiqui, Waseeq Ahmad
Parvez, Masood
2-[2-(3-Chloro­phen­yl)-2-oxoeth­yl]-4-hy­droxy-3-(3-meth­oxy­benzo­yl)-2H-1λ(6),2-benzothia­zine-1,1-dione
title 2-[2-(3-Chloro­phen­yl)-2-oxoeth­yl]-4-hy­droxy-3-(3-meth­oxy­benzo­yl)-2H-1λ(6),2-benzothia­zine-1,1-dione
title_full 2-[2-(3-Chloro­phen­yl)-2-oxoeth­yl]-4-hy­droxy-3-(3-meth­oxy­benzo­yl)-2H-1λ(6),2-benzothia­zine-1,1-dione
title_fullStr 2-[2-(3-Chloro­phen­yl)-2-oxoeth­yl]-4-hy­droxy-3-(3-meth­oxy­benzo­yl)-2H-1λ(6),2-benzothia­zine-1,1-dione
title_full_unstemmed 2-[2-(3-Chloro­phen­yl)-2-oxoeth­yl]-4-hy­droxy-3-(3-meth­oxy­benzo­yl)-2H-1λ(6),2-benzothia­zine-1,1-dione
title_short 2-[2-(3-Chloro­phen­yl)-2-oxoeth­yl]-4-hy­droxy-3-(3-meth­oxy­benzo­yl)-2H-1λ(6),2-benzothia­zine-1,1-dione
title_sort 2-[2-(3-chloro­phen­yl)-2-oxoeth­yl]-4-hy­droxy-3-(3-meth­oxy­benzo­yl)-2h-1λ(6),2-benzothia­zine-1,1-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343952/
https://www.ncbi.nlm.nih.gov/pubmed/22590033
http://dx.doi.org/10.1107/S1600536812009014
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