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4-Methoxy-N-(4-nitrobenzyl)aniline
In the title compound, C(14)H(14)N(2)O(3), the nitro group is nearly coplanar with the benzene ring to which it is bonded [dihedral angle = 1.70 (2)°], and this ring is para-substituted by the aminomethylene group. The dihedral angle between the benzene rings is 57.8 (1)°. The crystal structure is...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343958/ https://www.ncbi.nlm.nih.gov/pubmed/22590039 http://dx.doi.org/10.1107/S160053681200846X |
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author | Kapoor, Kamini Gupta, Vivek K. Kumar, Indresh Mir, Nisar A. Kant, Rajni |
author_facet | Kapoor, Kamini Gupta, Vivek K. Kumar, Indresh Mir, Nisar A. Kant, Rajni |
author_sort | Kapoor, Kamini |
collection | PubMed |
description | In the title compound, C(14)H(14)N(2)O(3), the nitro group is nearly coplanar with the benzene ring to which it is bonded [dihedral angle = 1.70 (2)°], and this ring is para-substituted by the aminomethylene group. The dihedral angle between the benzene rings is 57.8 (1)°. The crystal structure is stabilized by N—H⋯O and C—H⋯O hydrogen bonds and weak C—H⋯π interactions are also observed. |
format | Online Article Text |
id | pubmed-3343958 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33439582012-05-15 4-Methoxy-N-(4-nitrobenzyl)aniline Kapoor, Kamini Gupta, Vivek K. Kumar, Indresh Mir, Nisar A. Kant, Rajni Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(14)N(2)O(3), the nitro group is nearly coplanar with the benzene ring to which it is bonded [dihedral angle = 1.70 (2)°], and this ring is para-substituted by the aminomethylene group. The dihedral angle between the benzene rings is 57.8 (1)°. The crystal structure is stabilized by N—H⋯O and C—H⋯O hydrogen bonds and weak C—H⋯π interactions are also observed. International Union of Crystallography 2012-03-07 /pmc/articles/PMC3343958/ /pubmed/22590039 http://dx.doi.org/10.1107/S160053681200846X Text en © Kapoor et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kapoor, Kamini Gupta, Vivek K. Kumar, Indresh Mir, Nisar A. Kant, Rajni 4-Methoxy-N-(4-nitrobenzyl)aniline |
title | 4-Methoxy-N-(4-nitrobenzyl)aniline |
title_full | 4-Methoxy-N-(4-nitrobenzyl)aniline |
title_fullStr | 4-Methoxy-N-(4-nitrobenzyl)aniline |
title_full_unstemmed | 4-Methoxy-N-(4-nitrobenzyl)aniline |
title_short | 4-Methoxy-N-(4-nitrobenzyl)aniline |
title_sort | 4-methoxy-n-(4-nitrobenzyl)aniline |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343958/ https://www.ncbi.nlm.nih.gov/pubmed/22590039 http://dx.doi.org/10.1107/S160053681200846X |
work_keys_str_mv | AT kapoorkamini 4methoxyn4nitrobenzylaniline AT guptavivekk 4methoxyn4nitrobenzylaniline AT kumarindresh 4methoxyn4nitrobenzylaniline AT mirnisara 4methoxyn4nitrobenzylaniline AT kantrajni 4methoxyn4nitrobenzylaniline |