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2-Amino-3-chloro-5-nitrobenzamide
The amide group in the title compound, C(7)H(6)ClN(3)O(3), is significantly twisted out of the plane of the benzene ring [C—C—C—O = 34.2 (5)°] whereas the nitro group is almost co-planar [O—N—C—C = 4.0 (5)°] with the ring. Intramolecular N—H⋯O and N—H⋯Cl hydrogen bonds occur. In the crystal, the mo...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343961/ https://www.ncbi.nlm.nih.gov/pubmed/22590042 http://dx.doi.org/10.1107/S1600536812009142 |
| _version_ | 1782231883835244544 |
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| author | Wardell, James L. Tiekink, Edward R. T. |
| author_facet | Wardell, James L. Tiekink, Edward R. T. |
| author_sort | Wardell, James L. |
| collection | PubMed |
| description | The amide group in the title compound, C(7)H(6)ClN(3)O(3), is significantly twisted out of the plane of the benzene ring [C—C—C—O = 34.2 (5)°] whereas the nitro group is almost co-planar [O—N—C—C = 4.0 (5)°] with the ring. Intramolecular N—H⋯O and N—H⋯Cl hydrogen bonds occur. In the crystal, the molecules are linked by N—H⋯O hydrogen bonds, generating layers propagating in the ab plane. |
| format | Online Article Text |
| id | pubmed-3343961 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33439612012-05-15 2-Amino-3-chloro-5-nitrobenzamide Wardell, James L. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The amide group in the title compound, C(7)H(6)ClN(3)O(3), is significantly twisted out of the plane of the benzene ring [C—C—C—O = 34.2 (5)°] whereas the nitro group is almost co-planar [O—N—C—C = 4.0 (5)°] with the ring. Intramolecular N—H⋯O and N—H⋯Cl hydrogen bonds occur. In the crystal, the molecules are linked by N—H⋯O hydrogen bonds, generating layers propagating in the ab plane. International Union of Crystallography 2012-03-10 /pmc/articles/PMC3343961/ /pubmed/22590042 http://dx.doi.org/10.1107/S1600536812009142 Text en © Wardell and Tiekink 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Wardell, James L. Tiekink, Edward R. T. 2-Amino-3-chloro-5-nitrobenzamide |
| title | 2-Amino-3-chloro-5-nitrobenzamide |
| title_full | 2-Amino-3-chloro-5-nitrobenzamide |
| title_fullStr | 2-Amino-3-chloro-5-nitrobenzamide |
| title_full_unstemmed | 2-Amino-3-chloro-5-nitrobenzamide |
| title_short | 2-Amino-3-chloro-5-nitrobenzamide |
| title_sort | 2-amino-3-chloro-5-nitrobenzamide |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343961/ https://www.ncbi.nlm.nih.gov/pubmed/22590042 http://dx.doi.org/10.1107/S1600536812009142 |
| work_keys_str_mv | AT wardelljamesl 2amino3chloro5nitrobenzamide AT tiekinkedwardrt 2amino3chloro5nitrobenzamide |