2,2,2-Trifluoro-N-(4-methyl-2-oxo-2H-chromen-7-yl)acetamide

In the title mol­ecule, C(12)H(8)F(3)NO(3), the trifluoro­methyl group is rotationally disordered over three orientations in a 0.5:0.3:0.2 ratio. In the crystal, N—H⋯O hydrogen bonds link the mol­ecules related by translation into chains along the c axis. The crystal packing exhibits π–π inter­actio...

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Detalles Bibliográficos
Autores principales: Li, Hong-Da, Yin, Bing-Zhu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343970/
https://www.ncbi.nlm.nih.gov/pubmed/22589879
http://dx.doi.org/10.1107/S1600536812009634
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author Li, Hong-Da
Yin, Bing-Zhu
author_facet Li, Hong-Da
Yin, Bing-Zhu
author_sort Li, Hong-Da
collection PubMed
description In the title mol­ecule, C(12)H(8)F(3)NO(3), the trifluoro­methyl group is rotationally disordered over three orientations in a 0.5:0.3:0.2 ratio. In the crystal, N—H⋯O hydrogen bonds link the mol­ecules related by translation into chains along the c axis. The crystal packing exhibits π–π inter­actions between the pyran rings of neighboring mol­ecules [centroid–centroid distance = 3.462 (4) Å] and short C⋯O contacts of 3.149 (4) Å.
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spelling pubmed-33439702012-05-15 2,2,2-Trifluoro-N-(4-methyl-2-oxo-2H-chromen-7-yl)acetamide Li, Hong-Da Yin, Bing-Zhu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(12)H(8)F(3)NO(3), the trifluoro­methyl group is rotationally disordered over three orientations in a 0.5:0.3:0.2 ratio. In the crystal, N—H⋯O hydrogen bonds link the mol­ecules related by translation into chains along the c axis. The crystal packing exhibits π–π inter­actions between the pyran rings of neighboring mol­ecules [centroid–centroid distance = 3.462 (4) Å] and short C⋯O contacts of 3.149 (4) Å. International Union of Crystallography 2012-03-10 /pmc/articles/PMC3343970/ /pubmed/22589879 http://dx.doi.org/10.1107/S1600536812009634 Text en © Li and Yin 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Hong-Da
Yin, Bing-Zhu
2,2,2-Trifluoro-N-(4-methyl-2-oxo-2H-chromen-7-yl)acetamide
title 2,2,2-Trifluoro-N-(4-methyl-2-oxo-2H-chromen-7-yl)acetamide
title_full 2,2,2-Trifluoro-N-(4-methyl-2-oxo-2H-chromen-7-yl)acetamide
title_fullStr 2,2,2-Trifluoro-N-(4-methyl-2-oxo-2H-chromen-7-yl)acetamide
title_full_unstemmed 2,2,2-Trifluoro-N-(4-methyl-2-oxo-2H-chromen-7-yl)acetamide
title_short 2,2,2-Trifluoro-N-(4-methyl-2-oxo-2H-chromen-7-yl)acetamide
title_sort 2,2,2-trifluoro-n-(4-methyl-2-oxo-2h-chromen-7-yl)acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343970/
https://www.ncbi.nlm.nih.gov/pubmed/22589879
http://dx.doi.org/10.1107/S1600536812009634
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AT yinbingzhu 222trifluoron4methyl2oxo2hchromen7ylacetamide

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