(6Z)-4-Bromo-6-{[(2-hy­droxy­eth­yl)amino]­methyl­idene}cyclo­hexa-2,4-dien-1-one

The title mol­ecule, C(9)H(10)BrNO(2), excluding methyl­ene H atoms and the C—OH group, is essentially planar, with a maximum deviation of 0.037 (2) Å for the N atom. The N—C—C—O torsion angle is −63.1 (3)°. The mol­ecular structure is stabilized by a weak intra­molecular N—H⋯O(carbonyl) hydrogen bo...

Descripción completa

Detalles Bibliográficos
Autores principales: Mohamed, Shaaban K., Akkurt, Mehmet, Elhamid, Antar A. Abd, Singh, Kuldip, Potgieter, Herman
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343984/
https://www.ncbi.nlm.nih.gov/pubmed/22589893
http://dx.doi.org/10.1107/S1600536812009749
_version_ 1782231889045618688
author Mohamed, Shaaban K.
Akkurt, Mehmet
Elhamid, Antar A. Abd
Singh, Kuldip
Potgieter, Herman
author_facet Mohamed, Shaaban K.
Akkurt, Mehmet
Elhamid, Antar A. Abd
Singh, Kuldip
Potgieter, Herman
author_sort Mohamed, Shaaban K.
collection PubMed
description The title mol­ecule, C(9)H(10)BrNO(2), excluding methyl­ene H atoms and the C—OH group, is essentially planar, with a maximum deviation of 0.037 (2) Å for the N atom. The N—C—C—O torsion angle is −63.1 (3)°. The mol­ecular structure is stabilized by a weak intra­molecular N—H⋯O(carbonyl) hydrogen bond, forming an S(6) motif. In the crystal, mol­ecules are linked by O—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional network.
format Online
Article
Text
id pubmed-3343984
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33439842012-05-15 (6Z)-4-Bromo-6-{[(2-hy­droxy­eth­yl)amino]­methyl­idene}cyclo­hexa-2,4-dien-1-one Mohamed, Shaaban K. Akkurt, Mehmet Elhamid, Antar A. Abd Singh, Kuldip Potgieter, Herman Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(9)H(10)BrNO(2), excluding methyl­ene H atoms and the C—OH group, is essentially planar, with a maximum deviation of 0.037 (2) Å for the N atom. The N—C—C—O torsion angle is −63.1 (3)°. The mol­ecular structure is stabilized by a weak intra­molecular N—H⋯O(carbonyl) hydrogen bond, forming an S(6) motif. In the crystal, mol­ecules are linked by O—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2012-03-10 /pmc/articles/PMC3343984/ /pubmed/22589893 http://dx.doi.org/10.1107/S1600536812009749 Text en © Mohamed et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mohamed, Shaaban K.
Akkurt, Mehmet
Elhamid, Antar A. Abd
Singh, Kuldip
Potgieter, Herman
(6Z)-4-Bromo-6-{[(2-hy­droxy­eth­yl)amino]­methyl­idene}cyclo­hexa-2,4-dien-1-one
title (6Z)-4-Bromo-6-{[(2-hy­droxy­eth­yl)amino]­methyl­idene}cyclo­hexa-2,4-dien-1-one
title_full (6Z)-4-Bromo-6-{[(2-hy­droxy­eth­yl)amino]­methyl­idene}cyclo­hexa-2,4-dien-1-one
title_fullStr (6Z)-4-Bromo-6-{[(2-hy­droxy­eth­yl)amino]­methyl­idene}cyclo­hexa-2,4-dien-1-one
title_full_unstemmed (6Z)-4-Bromo-6-{[(2-hy­droxy­eth­yl)amino]­methyl­idene}cyclo­hexa-2,4-dien-1-one
title_short (6Z)-4-Bromo-6-{[(2-hy­droxy­eth­yl)amino]­methyl­idene}cyclo­hexa-2,4-dien-1-one
title_sort (6z)-4-bromo-6-{[(2-hy­droxy­eth­yl)amino]­methyl­idene}cyclo­hexa-2,4-dien-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343984/
https://www.ncbi.nlm.nih.gov/pubmed/22589893
http://dx.doi.org/10.1107/S1600536812009749
work_keys_str_mv AT mohamedshaabank 6z4bromo62hydroxyethylaminomethylidenecyclohexa24dien1one
AT akkurtmehmet 6z4bromo62hydroxyethylaminomethylidenecyclohexa24dien1one
AT elhamidantaraabd 6z4bromo62hydroxyethylaminomethylidenecyclohexa24dien1one
AT singhkuldip 6z4bromo62hydroxyethylaminomethylidenecyclohexa24dien1one
AT potgieterherman 6z4bromo62hydroxyethylaminomethylidenecyclohexa24dien1one

Ejemplares similares