N,N′-Bis[(E)-1-(thio­phen-3-yl)ethyl­idene]ethane-1,2-diamine

The complete mol­ecule of the title compound, C(14)H(16)N(2)S(2), is generated by a crystallographic inversion centre. The thio­phene residue is close to being coplanar with the imine group [C—C—C—N torsion angle = 6.5 (2)°], and the conformation about the imine C=N bond [1.281 (2) Å] is E. In the c...

Descripción completa

Detalles Bibliográficos
Autores principales: Asiri, Abdullah M., Faidallah, Hassan M., Khan, Khalid A., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343990/
https://www.ncbi.nlm.nih.gov/pubmed/22589899
http://dx.doi.org/10.1107/S1600536812009798
_version_ 1782231890430787584
author Asiri, Abdullah M.
Faidallah, Hassan M.
Khan, Khalid A.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Asiri, Abdullah M.
Faidallah, Hassan M.
Khan, Khalid A.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Asiri, Abdullah M.
collection PubMed
description The complete mol­ecule of the title compound, C(14)H(16)N(2)S(2), is generated by a crystallographic inversion centre. The thio­phene residue is close to being coplanar with the imine group [C—C—C—N torsion angle = 6.5 (2)°], and the conformation about the imine C=N bond [1.281 (2) Å] is E. In the crystal, the three-dimensional architecture is consolidated by C—H⋯N, C—H⋯π and S⋯S [3.3932 (7) Å] inter­actions.
format Online
Article
Text
id pubmed-3343990
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33439902012-05-15 N,N′-Bis[(E)-1-(thio­phen-3-yl)ethyl­idene]ethane-1,2-diamine Asiri, Abdullah M. Faidallah, Hassan M. Khan, Khalid A. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The complete mol­ecule of the title compound, C(14)H(16)N(2)S(2), is generated by a crystallographic inversion centre. The thio­phene residue is close to being coplanar with the imine group [C—C—C—N torsion angle = 6.5 (2)°], and the conformation about the imine C=N bond [1.281 (2) Å] is E. In the crystal, the three-dimensional architecture is consolidated by C—H⋯N, C—H⋯π and S⋯S [3.3932 (7) Å] inter­actions. International Union of Crystallography 2012-03-10 /pmc/articles/PMC3343990/ /pubmed/22589899 http://dx.doi.org/10.1107/S1600536812009798 Text en © Asiri et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Asiri, Abdullah M.
Faidallah, Hassan M.
Khan, Khalid A.
Ng, Seik Weng
Tiekink, Edward R. T.
N,N′-Bis[(E)-1-(thio­phen-3-yl)ethyl­idene]ethane-1,2-diamine
title N,N′-Bis[(E)-1-(thio­phen-3-yl)ethyl­idene]ethane-1,2-diamine
title_full N,N′-Bis[(E)-1-(thio­phen-3-yl)ethyl­idene]ethane-1,2-diamine
title_fullStr N,N′-Bis[(E)-1-(thio­phen-3-yl)ethyl­idene]ethane-1,2-diamine
title_full_unstemmed N,N′-Bis[(E)-1-(thio­phen-3-yl)ethyl­idene]ethane-1,2-diamine
title_short N,N′-Bis[(E)-1-(thio­phen-3-yl)ethyl­idene]ethane-1,2-diamine
title_sort n,n′-bis[(e)-1-(thio­phen-3-yl)ethyl­idene]ethane-1,2-diamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343990/
https://www.ncbi.nlm.nih.gov/pubmed/22589899
http://dx.doi.org/10.1107/S1600536812009798
work_keys_str_mv AT asiriabdullahm nnbise1thiophen3ylethylideneethane12diamine
AT faidallahhassanm nnbise1thiophen3ylethylideneethane12diamine
AT khankhalida nnbise1thiophen3ylethylideneethane12diamine
AT ngseikweng nnbise1thiophen3ylethylideneethane12diamine
AT tiekinkedwardrt nnbise1thiophen3ylethylideneethane12diamine

Ejemplares similares