Ethyl 2-(7-oxo-3,5-diphenyl-1,4-diaze­pan-2-yl)acetate

In the title compound, C(21)H(24)N(2)O(3), the diazepane ring adopts a chair conformation. The central diazepane ring forms dihedral angles 67.80 (7) and 72.29 (5)° with the two benzene rings. The eth­oxy­carbonyl group is disordered over two conformations with site-occupancy factors of 0.643 (5) an...

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Autores principales: Jagadeesan, G., Sethusankar, K., Selvakumar, P., Thennarasu, S., Mandal, A. B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343996/
https://www.ncbi.nlm.nih.gov/pubmed/22589905
http://dx.doi.org/10.1107/S160053681200757X
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author Jagadeesan, G.
Sethusankar, K.
Selvakumar, P.
Thennarasu, S.
Mandal, A. B.
author_facet Jagadeesan, G.
Sethusankar, K.
Selvakumar, P.
Thennarasu, S.
Mandal, A. B.
author_sort Jagadeesan, G.
collection PubMed
description In the title compound, C(21)H(24)N(2)O(3), the diazepane ring adopts a chair conformation. The central diazepane ring forms dihedral angles 67.80 (7) and 72.29 (5)° with the two benzene rings. The eth­oxy­carbonyl group is disordered over two conformations with site-occupancy factors of 0.643 (5) and 0.357 (5). In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops.
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spelling pubmed-33439962012-05-15 Ethyl 2-(7-oxo-3,5-diphenyl-1,4-diaze­pan-2-yl)acetate Jagadeesan, G. Sethusankar, K. Selvakumar, P. Thennarasu, S. Mandal, A. B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(24)N(2)O(3), the diazepane ring adopts a chair conformation. The central diazepane ring forms dihedral angles 67.80 (7) and 72.29 (5)° with the two benzene rings. The eth­oxy­carbonyl group is disordered over two conformations with site-occupancy factors of 0.643 (5) and 0.357 (5). In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops. International Union of Crystallography 2012-03-10 /pmc/articles/PMC3343996/ /pubmed/22589905 http://dx.doi.org/10.1107/S160053681200757X Text en © Jagadeesan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jagadeesan, G.
Sethusankar, K.
Selvakumar, P.
Thennarasu, S.
Mandal, A. B.
Ethyl 2-(7-oxo-3,5-diphenyl-1,4-diaze­pan-2-yl)acetate
title Ethyl 2-(7-oxo-3,5-diphenyl-1,4-diaze­pan-2-yl)acetate
title_full Ethyl 2-(7-oxo-3,5-diphenyl-1,4-diaze­pan-2-yl)acetate
title_fullStr Ethyl 2-(7-oxo-3,5-diphenyl-1,4-diaze­pan-2-yl)acetate
title_full_unstemmed Ethyl 2-(7-oxo-3,5-diphenyl-1,4-diaze­pan-2-yl)acetate
title_short Ethyl 2-(7-oxo-3,5-diphenyl-1,4-diaze­pan-2-yl)acetate
title_sort ethyl 2-(7-oxo-3,5-diphenyl-1,4-diaze­pan-2-yl)acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343996/
https://www.ncbi.nlm.nih.gov/pubmed/22589905
http://dx.doi.org/10.1107/S160053681200757X
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AT sethusankark ethyl27oxo35diphenyl14diazepan2ylacetate
AT selvakumarp ethyl27oxo35diphenyl14diazepan2ylacetate
AT thennarasus ethyl27oxo35diphenyl14diazepan2ylacetate
AT mandalab ethyl27oxo35diphenyl14diazepan2ylacetate

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