(E)-3-[(3-Eth­oxy-2-hy­droxy­benzyl­idene)amino]­benzoic acid

In the title compound, C(16)H(15)NO(4), a potential bidentate N,O-donor Schiff base ligand, the benzene rings are inclined to one another by 4.24 (12)°. The mol­ecule has an E conformation about the C=N bond. An intra­molecular O—H⋯N hydrogen bond makes an S(6) ring motif. In the crystal, pairs of O...

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Detalles Bibliográficos
Autores principales: Kargar, Hadi, Sharafi, Zahra, Kia, Reza, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343997/
https://www.ncbi.nlm.nih.gov/pubmed/22589906
http://dx.doi.org/10.1107/S1600536812009968
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author Kargar, Hadi
Sharafi, Zahra
Kia, Reza
Tahir, Muhammad Nawaz
author_facet Kargar, Hadi
Sharafi, Zahra
Kia, Reza
Tahir, Muhammad Nawaz
author_sort Kargar, Hadi
collection PubMed
description In the title compound, C(16)H(15)NO(4), a potential bidentate N,O-donor Schiff base ligand, the benzene rings are inclined to one another by 4.24 (12)°. The mol­ecule has an E conformation about the C=N bond. An intra­molecular O—H⋯N hydrogen bond makes an S(6) ring motif. In the crystal, pairs of O—H⋯O hydrogen bonds link the mol­ecules, forming inversion dimers with R (2) (2)(8) ring motifs. These dimers are further connected by C—H⋯O inter­actions, forming a sheet in (104). There is also a C—H⋯π inter­action present involving neighbouring mol­ecules.
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spelling pubmed-33439972012-05-15 (E)-3-[(3-Eth­oxy-2-hy­droxy­benzyl­idene)amino]­benzoic acid Kargar, Hadi Sharafi, Zahra Kia, Reza Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(15)NO(4), a potential bidentate N,O-donor Schiff base ligand, the benzene rings are inclined to one another by 4.24 (12)°. The mol­ecule has an E conformation about the C=N bond. An intra­molecular O—H⋯N hydrogen bond makes an S(6) ring motif. In the crystal, pairs of O—H⋯O hydrogen bonds link the mol­ecules, forming inversion dimers with R (2) (2)(8) ring motifs. These dimers are further connected by C—H⋯O inter­actions, forming a sheet in (104). There is also a C—H⋯π inter­action present involving neighbouring mol­ecules. International Union of Crystallography 2012-03-10 /pmc/articles/PMC3343997/ /pubmed/22589906 http://dx.doi.org/10.1107/S1600536812009968 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kargar, Hadi
Sharafi, Zahra
Kia, Reza
Tahir, Muhammad Nawaz
(E)-3-[(3-Eth­oxy-2-hy­droxy­benzyl­idene)amino]­benzoic acid
title (E)-3-[(3-Eth­oxy-2-hy­droxy­benzyl­idene)amino]­benzoic acid
title_full (E)-3-[(3-Eth­oxy-2-hy­droxy­benzyl­idene)amino]­benzoic acid
title_fullStr (E)-3-[(3-Eth­oxy-2-hy­droxy­benzyl­idene)amino]­benzoic acid
title_full_unstemmed (E)-3-[(3-Eth­oxy-2-hy­droxy­benzyl­idene)amino]­benzoic acid
title_short (E)-3-[(3-Eth­oxy-2-hy­droxy­benzyl­idene)amino]­benzoic acid
title_sort (e)-3-[(3-eth­oxy-2-hy­droxy­benzyl­idene)amino]­benzoic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343997/
https://www.ncbi.nlm.nih.gov/pubmed/22589906
http://dx.doi.org/10.1107/S1600536812009968
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AT tahirmuhammadnawaz e33ethoxy2hydroxybenzylideneaminobenzoicacid

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