(E)-4-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-meth­oxy­phenyl 4-bromo­benzene­sulfonate

In the title compound, C(25)H(22)BrN(3)O(5)S, the central benzene ring makes dihedral angles of 4.41 (10), 67.09 (9) and 62.05 (10)°, respectively, with the pyrazolone, bromo­benzene and terminal phenyl rings. The dihedral angle between the pyrazolone and phenyl rings is 57.75 (11)°. In the crystal,...

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Detalles Bibliográficos
Autores principales: Duan, Zhong-Yu, Ma, Guo-Li, Yang, Li-Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344000/
https://www.ncbi.nlm.nih.gov/pubmed/22589909
http://dx.doi.org/10.1107/S1600536812010057
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author Duan, Zhong-Yu
Ma, Guo-Li
Yang, Li-Ping
author_facet Duan, Zhong-Yu
Ma, Guo-Li
Yang, Li-Ping
author_sort Duan, Zhong-Yu
collection PubMed
description In the title compound, C(25)H(22)BrN(3)O(5)S, the central benzene ring makes dihedral angles of 4.41 (10), 67.09 (9) and 62.05 (10)°, respectively, with the pyrazolone, bromo­benzene and terminal phenyl rings. The dihedral angle between the pyrazolone and phenyl rings is 57.75 (11)°. In the crystal, two pairs of C—H⋯O hydrogen bonds link the mol­ecules into inversion dimers. A weak intra­molecular C—H⋯O hydrogen bonds is also observed.
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spelling pubmed-33440002012-05-15 (E)-4-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-meth­oxy­phenyl 4-bromo­benzene­sulfonate Duan, Zhong-Yu Ma, Guo-Li Yang, Li-Ping Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(22)BrN(3)O(5)S, the central benzene ring makes dihedral angles of 4.41 (10), 67.09 (9) and 62.05 (10)°, respectively, with the pyrazolone, bromo­benzene and terminal phenyl rings. The dihedral angle between the pyrazolone and phenyl rings is 57.75 (11)°. In the crystal, two pairs of C—H⋯O hydrogen bonds link the mol­ecules into inversion dimers. A weak intra­molecular C—H⋯O hydrogen bonds is also observed. International Union of Crystallography 2012-03-10 /pmc/articles/PMC3344000/ /pubmed/22589909 http://dx.doi.org/10.1107/S1600536812010057 Text en © Duan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Duan, Zhong-Yu
Ma, Guo-Li
Yang, Li-Ping
(E)-4-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-meth­oxy­phenyl 4-bromo­benzene­sulfonate
title (E)-4-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-meth­oxy­phenyl 4-bromo­benzene­sulfonate
title_full (E)-4-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-meth­oxy­phenyl 4-bromo­benzene­sulfonate
title_fullStr (E)-4-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-meth­oxy­phenyl 4-bromo­benzene­sulfonate
title_full_unstemmed (E)-4-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-meth­oxy­phenyl 4-bromo­benzene­sulfonate
title_short (E)-4-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-meth­oxy­phenyl 4-bromo­benzene­sulfonate
title_sort (e)-4-[(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1h-pyrazol-4-yl)imino­meth­yl]-2-meth­oxy­phenyl 4-bromo­benzene­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344000/
https://www.ncbi.nlm.nih.gov/pubmed/22589909
http://dx.doi.org/10.1107/S1600536812010057
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AT yangliping e415dimethyl3oxo2phenyl23dihydro1hpyrazol4yliminomethyl2methoxyphenyl4bromobenzenesulfonate

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