4,6-Bis(diphenyl­phosphan­yl)-2,8-di­methyl­phenoxathiin dichloro­methane monosolvate

The title compound, C(38)H(30)OP(2)S·CH(2)Cl(2), belongs to the xanthene family of ligands containing S- and O-donor atoms in the central heterocylic ring. Positions 2 and 8 on the xanthene backbone are functionalized with methyl groups to allow for the selective functionalization of the backbone at...

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Detalles Bibliográficos
Autores principales: Marimuthu, Thashree, Friedrich, Holger B., Bala, Muhammad D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344001/
https://www.ncbi.nlm.nih.gov/pubmed/22589910
http://dx.doi.org/10.1107/S1600536812009920
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author Marimuthu, Thashree
Friedrich, Holger B.
Bala, Muhammad D.
author_facet Marimuthu, Thashree
Friedrich, Holger B.
Bala, Muhammad D.
author_sort Marimuthu, Thashree
collection PubMed
description The title compound, C(38)H(30)OP(2)S·CH(2)Cl(2), belongs to the xanthene family of ligands containing S- and O-donor atoms in the central heterocylic ring. Positions 2 and 8 on the xanthene backbone are functionalized with methyl groups to allow for the selective functionalization of the backbone at positions 4 and 6 with diphenyl­phosphanyl units. The title compound shows a significant ‘roof-like’ bending along the axis of planarity involving the O- and S-donor atoms and the benzene rings, resulting in a dihedral angle between the mean planes of the benzene rings of 32.88 (13)°.
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spelling pubmed-33440012012-05-15 4,6-Bis(diphenyl­phosphan­yl)-2,8-di­methyl­phenoxathiin dichloro­methane monosolvate Marimuthu, Thashree Friedrich, Holger B. Bala, Muhammad D. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(38)H(30)OP(2)S·CH(2)Cl(2), belongs to the xanthene family of ligands containing S- and O-donor atoms in the central heterocylic ring. Positions 2 and 8 on the xanthene backbone are functionalized with methyl groups to allow for the selective functionalization of the backbone at positions 4 and 6 with diphenyl­phosphanyl units. The title compound shows a significant ‘roof-like’ bending along the axis of planarity involving the O- and S-donor atoms and the benzene rings, resulting in a dihedral angle between the mean planes of the benzene rings of 32.88 (13)°. International Union of Crystallography 2012-03-10 /pmc/articles/PMC3344001/ /pubmed/22589910 http://dx.doi.org/10.1107/S1600536812009920 Text en © Marimuthu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Marimuthu, Thashree
Friedrich, Holger B.
Bala, Muhammad D.
4,6-Bis(diphenyl­phosphan­yl)-2,8-di­methyl­phenoxathiin dichloro­methane monosolvate
title 4,6-Bis(diphenyl­phosphan­yl)-2,8-di­methyl­phenoxathiin dichloro­methane monosolvate
title_full 4,6-Bis(diphenyl­phosphan­yl)-2,8-di­methyl­phenoxathiin dichloro­methane monosolvate
title_fullStr 4,6-Bis(diphenyl­phosphan­yl)-2,8-di­methyl­phenoxathiin dichloro­methane monosolvate
title_full_unstemmed 4,6-Bis(diphenyl­phosphan­yl)-2,8-di­methyl­phenoxathiin dichloro­methane monosolvate
title_short 4,6-Bis(diphenyl­phosphan­yl)-2,8-di­methyl­phenoxathiin dichloro­methane monosolvate
title_sort 4,6-bis(diphenyl­phosphan­yl)-2,8-di­methyl­phenoxathiin dichloro­methane monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344001/
https://www.ncbi.nlm.nih.gov/pubmed/22589910
http://dx.doi.org/10.1107/S1600536812009920
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