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1-(4-Chlorophenyl)-2-[4-hydroxy-3-(3-methoxybenzoyl)-1,1-dioxo-2H-1λ(6),2-benzothiazin-2-yl]ethanone
In the title molecule, C(24)H(18)ClNO(6)S, the heterocyclic thiazine ring adopts a half-chair conformation with the S and N atoms displaced by 0.406 (5) and 0.444 (5) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The methoxybenzoyl and the chlorophenyl...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344017/ https://www.ncbi.nlm.nih.gov/pubmed/22589926 http://dx.doi.org/10.1107/S160053681201029X |
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author | Siddiqui, Hamid Latif Ahmad, Matloob Gul, Salman Ashraf, Chaudhary Muhammad Parvez, Masood |
author_facet | Siddiqui, Hamid Latif Ahmad, Matloob Gul, Salman Ashraf, Chaudhary Muhammad Parvez, Masood |
author_sort | Siddiqui, Hamid Latif |
collection | PubMed |
description | In the title molecule, C(24)H(18)ClNO(6)S, the heterocyclic thiazine ring adopts a half-chair conformation with the S and N atoms displaced by 0.406 (5) and 0.444 (5) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The methoxybenzoyl and the chlorophenyl rings lie roughly parallel to each other, with a dihedral angle between the mean planes of these rings of 8.86 (10)°. The molecular structure is consolidated by intramolecular O—H⋯O and C—H⋯O interactions and the crystal packing is stabilized by intermolecular O—H⋯O and C—H⋯Cl hydrogen bonds. |
format | Online Article Text |
id | pubmed-3344017 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33440172012-05-15 1-(4-Chlorophenyl)-2-[4-hydroxy-3-(3-methoxybenzoyl)-1,1-dioxo-2H-1λ(6),2-benzothiazin-2-yl]ethanone Siddiqui, Hamid Latif Ahmad, Matloob Gul, Salman Ashraf, Chaudhary Muhammad Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(24)H(18)ClNO(6)S, the heterocyclic thiazine ring adopts a half-chair conformation with the S and N atoms displaced by 0.406 (5) and 0.444 (5) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The methoxybenzoyl and the chlorophenyl rings lie roughly parallel to each other, with a dihedral angle between the mean planes of these rings of 8.86 (10)°. The molecular structure is consolidated by intramolecular O—H⋯O and C—H⋯O interactions and the crystal packing is stabilized by intermolecular O—H⋯O and C—H⋯Cl hydrogen bonds. International Union of Crystallography 2012-03-14 /pmc/articles/PMC3344017/ /pubmed/22589926 http://dx.doi.org/10.1107/S160053681201029X Text en © Siddiqui et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Siddiqui, Hamid Latif Ahmad, Matloob Gul, Salman Ashraf, Chaudhary Muhammad Parvez, Masood 1-(4-Chlorophenyl)-2-[4-hydroxy-3-(3-methoxybenzoyl)-1,1-dioxo-2H-1λ(6),2-benzothiazin-2-yl]ethanone |
title | 1-(4-Chlorophenyl)-2-[4-hydroxy-3-(3-methoxybenzoyl)-1,1-dioxo-2H-1λ(6),2-benzothiazin-2-yl]ethanone |
title_full | 1-(4-Chlorophenyl)-2-[4-hydroxy-3-(3-methoxybenzoyl)-1,1-dioxo-2H-1λ(6),2-benzothiazin-2-yl]ethanone |
title_fullStr | 1-(4-Chlorophenyl)-2-[4-hydroxy-3-(3-methoxybenzoyl)-1,1-dioxo-2H-1λ(6),2-benzothiazin-2-yl]ethanone |
title_full_unstemmed | 1-(4-Chlorophenyl)-2-[4-hydroxy-3-(3-methoxybenzoyl)-1,1-dioxo-2H-1λ(6),2-benzothiazin-2-yl]ethanone |
title_short | 1-(4-Chlorophenyl)-2-[4-hydroxy-3-(3-methoxybenzoyl)-1,1-dioxo-2H-1λ(6),2-benzothiazin-2-yl]ethanone |
title_sort | 1-(4-chlorophenyl)-2-[4-hydroxy-3-(3-methoxybenzoyl)-1,1-dioxo-2h-1λ(6),2-benzothiazin-2-yl]ethanone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344017/ https://www.ncbi.nlm.nih.gov/pubmed/22589926 http://dx.doi.org/10.1107/S160053681201029X |
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