Cargando…

1-(4-Chloro­phen­yl)-2-[4-hy­droxy-3-(3-meth­oxy­benzo­yl)-1,1-dioxo-2H-1λ(6),2-benzothia­zin-2-yl]ethanone

In the title mol­ecule, C(24)H(18)ClNO(6)S, the heterocyclic thia­zine ring adopts a half-chair conformation with the S and N atoms displaced by 0.406 (5) and 0.444 (5) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The meth­oxy­benzoyl and the chloro­phenyl...

Descripción completa

Detalles Bibliográficos
Autores principales: Siddiqui, Hamid Latif, Ahmad, Matloob, Gul, Salman, Ashraf, Chaudhary Muhammad, Parvez, Masood
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344017/
https://www.ncbi.nlm.nih.gov/pubmed/22589926
http://dx.doi.org/10.1107/S160053681201029X
_version_ 1782231896719097856
author Siddiqui, Hamid Latif
Ahmad, Matloob
Gul, Salman
Ashraf, Chaudhary Muhammad
Parvez, Masood
author_facet Siddiqui, Hamid Latif
Ahmad, Matloob
Gul, Salman
Ashraf, Chaudhary Muhammad
Parvez, Masood
author_sort Siddiqui, Hamid Latif
collection PubMed
description In the title mol­ecule, C(24)H(18)ClNO(6)S, the heterocyclic thia­zine ring adopts a half-chair conformation with the S and N atoms displaced by 0.406 (5) and 0.444 (5) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The meth­oxy­benzoyl and the chloro­phenyl rings lie roughly parallel to each other, with a dihedral angle between the mean planes of these rings of 8.86 (10)°. The mol­ecular structure is consolidated by intra­molecular O—H⋯O and C—H⋯O inter­actions and the crystal packing is stabilized by inter­molecular O—H⋯O and C—H⋯Cl hydrogen bonds.
format Online
Article
Text
id pubmed-3344017
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33440172012-05-15 1-(4-Chloro­phen­yl)-2-[4-hy­droxy-3-(3-meth­oxy­benzo­yl)-1,1-dioxo-2H-1λ(6),2-benzothia­zin-2-yl]ethanone Siddiqui, Hamid Latif Ahmad, Matloob Gul, Salman Ashraf, Chaudhary Muhammad Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(24)H(18)ClNO(6)S, the heterocyclic thia­zine ring adopts a half-chair conformation with the S and N atoms displaced by 0.406 (5) and 0.444 (5) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The meth­oxy­benzoyl and the chloro­phenyl rings lie roughly parallel to each other, with a dihedral angle between the mean planes of these rings of 8.86 (10)°. The mol­ecular structure is consolidated by intra­molecular O—H⋯O and C—H⋯O inter­actions and the crystal packing is stabilized by inter­molecular O—H⋯O and C—H⋯Cl hydrogen bonds. International Union of Crystallography 2012-03-14 /pmc/articles/PMC3344017/ /pubmed/22589926 http://dx.doi.org/10.1107/S160053681201029X Text en © Siddiqui et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Siddiqui, Hamid Latif
Ahmad, Matloob
Gul, Salman
Ashraf, Chaudhary Muhammad
Parvez, Masood
1-(4-Chloro­phen­yl)-2-[4-hy­droxy-3-(3-meth­oxy­benzo­yl)-1,1-dioxo-2H-1λ(6),2-benzothia­zin-2-yl]ethanone
title 1-(4-Chloro­phen­yl)-2-[4-hy­droxy-3-(3-meth­oxy­benzo­yl)-1,1-dioxo-2H-1λ(6),2-benzothia­zin-2-yl]ethanone
title_full 1-(4-Chloro­phen­yl)-2-[4-hy­droxy-3-(3-meth­oxy­benzo­yl)-1,1-dioxo-2H-1λ(6),2-benzothia­zin-2-yl]ethanone
title_fullStr 1-(4-Chloro­phen­yl)-2-[4-hy­droxy-3-(3-meth­oxy­benzo­yl)-1,1-dioxo-2H-1λ(6),2-benzothia­zin-2-yl]ethanone
title_full_unstemmed 1-(4-Chloro­phen­yl)-2-[4-hy­droxy-3-(3-meth­oxy­benzo­yl)-1,1-dioxo-2H-1λ(6),2-benzothia­zin-2-yl]ethanone
title_short 1-(4-Chloro­phen­yl)-2-[4-hy­droxy-3-(3-meth­oxy­benzo­yl)-1,1-dioxo-2H-1λ(6),2-benzothia­zin-2-yl]ethanone
title_sort 1-(4-chloro­phen­yl)-2-[4-hy­droxy-3-(3-meth­oxy­benzo­yl)-1,1-dioxo-2h-1λ(6),2-benzothia­zin-2-yl]ethanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344017/
https://www.ncbi.nlm.nih.gov/pubmed/22589926
http://dx.doi.org/10.1107/S160053681201029X
work_keys_str_mv AT siddiquihamidlatif 14chlorophenyl24hydroxy33methoxybenzoyl11dioxo2h1l62benzothiazin2ylethanone
AT ahmadmatloob 14chlorophenyl24hydroxy33methoxybenzoyl11dioxo2h1l62benzothiazin2ylethanone
AT gulsalman 14chlorophenyl24hydroxy33methoxybenzoyl11dioxo2h1l62benzothiazin2ylethanone
AT ashrafchaudharymuhammad 14chlorophenyl24hydroxy33methoxybenzoyl11dioxo2h1l62benzothiazin2ylethanone
AT parvezmasood 14chlorophenyl24hydroxy33methoxybenzoyl11dioxo2h1l62benzothiazin2ylethanone