Methyl 2-{[(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl­idene)(4-nitro­phen­yl)meth­yl]amino}-3-phenyl­propano­ate

The mol­ecule of the title compound, C(27)H(24)N(4)O(5), exists in the keto–enamine tautomeric form, stabilized by an intra­molecular N—H⋯O hydrogen bond. An intra­molecular C—H⋯·O hydrogen bond also occurs. In the crystal, C—H⋯O hydrogen bonds link the mol­ecules into chains.

Detalles Bibliográficos
Autores principales: Zhang, Xin, Sun, Chen, Li, Fei-ran, Zhang, Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344020/
https://www.ncbi.nlm.nih.gov/pubmed/22589929
http://dx.doi.org/10.1107/S1600536812010343
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author Zhang, Xin
Sun, Chen
Li, Fei-ran
Zhang, Hua
author_facet Zhang, Xin
Sun, Chen
Li, Fei-ran
Zhang, Hua
author_sort Zhang, Xin
collection PubMed
description The mol­ecule of the title compound, C(27)H(24)N(4)O(5), exists in the keto–enamine tautomeric form, stabilized by an intra­molecular N—H⋯O hydrogen bond. An intra­molecular C—H⋯·O hydrogen bond also occurs. In the crystal, C—H⋯O hydrogen bonds link the mol­ecules into chains.
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spelling pubmed-33440202012-05-15 Methyl 2-{[(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl­idene)(4-nitro­phen­yl)meth­yl]amino}-3-phenyl­propano­ate Zhang, Xin Sun, Chen Li, Fei-ran Zhang, Hua Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(27)H(24)N(4)O(5), exists in the keto–enamine tautomeric form, stabilized by an intra­molecular N—H⋯O hydrogen bond. An intra­molecular C—H⋯·O hydrogen bond also occurs. In the crystal, C—H⋯O hydrogen bonds link the mol­ecules into chains. International Union of Crystallography 2012-03-14 /pmc/articles/PMC3344020/ /pubmed/22589929 http://dx.doi.org/10.1107/S1600536812010343 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Xin
Sun, Chen
Li, Fei-ran
Zhang, Hua
Methyl 2-{[(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl­idene)(4-nitro­phen­yl)meth­yl]amino}-3-phenyl­propano­ate
title Methyl 2-{[(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl­idene)(4-nitro­phen­yl)meth­yl]amino}-3-phenyl­propano­ate
title_full Methyl 2-{[(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl­idene)(4-nitro­phen­yl)meth­yl]amino}-3-phenyl­propano­ate
title_fullStr Methyl 2-{[(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl­idene)(4-nitro­phen­yl)meth­yl]amino}-3-phenyl­propano­ate
title_full_unstemmed Methyl 2-{[(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl­idene)(4-nitro­phen­yl)meth­yl]amino}-3-phenyl­propano­ate
title_short Methyl 2-{[(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl­idene)(4-nitro­phen­yl)meth­yl]amino}-3-phenyl­propano­ate
title_sort methyl 2-{[(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1h-pyrazol-4-yl­idene)(4-nitro­phen­yl)meth­yl]amino}-3-phenyl­propano­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344020/
https://www.ncbi.nlm.nih.gov/pubmed/22589929
http://dx.doi.org/10.1107/S1600536812010343
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