Cargando…

(2E)-2-(Furan-2-yl­methyl­idene)-2,3-dihydro-1H-inden-1-one

In the title compound, C(14)H(10)O(2), the five-membered ring of the inden-1-one residue is almost planar (r.m.s. deviation = 0.035 Å). A twist about the single bond linking the two residues is evident [C—C—C—C torsion angle = −13.2 (5)°]. The three-dimensional architecture is stabilized by C—H⋯O (i...

Descripción completa

Detalles Bibliográficos
Autores principales: Asiri, Abdullah M., Faidallah, Hassan M., Al-Nemari, Khulud F., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344023/
https://www.ncbi.nlm.nih.gov/pubmed/22589932
http://dx.doi.org/10.1107/S1600536812010501
_version_ 1782231898088538112
author Asiri, Abdullah M.
Faidallah, Hassan M.
Al-Nemari, Khulud F.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Asiri, Abdullah M.
Faidallah, Hassan M.
Al-Nemari, Khulud F.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Asiri, Abdullah M.
collection PubMed
description In the title compound, C(14)H(10)O(2), the five-membered ring of the inden-1-one residue is almost planar (r.m.s. deviation = 0.035 Å). A twist about the single bond linking the two residues is evident [C—C—C—C torsion angle = −13.2 (5)°]. The three-dimensional architecture is stabilized by C—H⋯O (involving the trifurcated carbonyl O atom), C—H⋯π and π–π inter­actions [between the five- and six-membered rings of inden-1-one residues; ring centroid–centroid distance = 3.7983 (17) Å]. The sample studied was a non-merohedral twin; the minor component refined to approximately 36%.
format Online
Article
Text
id pubmed-3344023
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33440232012-05-15 (2E)-2-(Furan-2-yl­methyl­idene)-2,3-dihydro-1H-inden-1-one Asiri, Abdullah M. Faidallah, Hassan M. Al-Nemari, Khulud F. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(10)O(2), the five-membered ring of the inden-1-one residue is almost planar (r.m.s. deviation = 0.035 Å). A twist about the single bond linking the two residues is evident [C—C—C—C torsion angle = −13.2 (5)°]. The three-dimensional architecture is stabilized by C—H⋯O (involving the trifurcated carbonyl O atom), C—H⋯π and π–π inter­actions [between the five- and six-membered rings of inden-1-one residues; ring centroid–centroid distance = 3.7983 (17) Å]. The sample studied was a non-merohedral twin; the minor component refined to approximately 36%. International Union of Crystallography 2012-03-14 /pmc/articles/PMC3344023/ /pubmed/22589932 http://dx.doi.org/10.1107/S1600536812010501 Text en © Asiri et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Asiri, Abdullah M.
Faidallah, Hassan M.
Al-Nemari, Khulud F.
Ng, Seik Weng
Tiekink, Edward R. T.
(2E)-2-(Furan-2-yl­methyl­idene)-2,3-dihydro-1H-inden-1-one
title (2E)-2-(Furan-2-yl­methyl­idene)-2,3-dihydro-1H-inden-1-one
title_full (2E)-2-(Furan-2-yl­methyl­idene)-2,3-dihydro-1H-inden-1-one
title_fullStr (2E)-2-(Furan-2-yl­methyl­idene)-2,3-dihydro-1H-inden-1-one
title_full_unstemmed (2E)-2-(Furan-2-yl­methyl­idene)-2,3-dihydro-1H-inden-1-one
title_short (2E)-2-(Furan-2-yl­methyl­idene)-2,3-dihydro-1H-inden-1-one
title_sort (2e)-2-(furan-2-yl­methyl­idene)-2,3-dihydro-1h-inden-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344023/
https://www.ncbi.nlm.nih.gov/pubmed/22589932
http://dx.doi.org/10.1107/S1600536812010501
work_keys_str_mv AT asiriabdullahm 2e2furan2ylmethylidene23dihydro1hinden1one
AT faidallahhassanm 2e2furan2ylmethylidene23dihydro1hinden1one
AT alnemarikhuludf 2e2furan2ylmethylidene23dihydro1hinden1one
AT ngseikweng 2e2furan2ylmethylidene23dihydro1hinden1one
AT tiekinkedwardrt 2e2furan2ylmethylidene23dihydro1hinden1one