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(2E)-2-(Furan-2-ylmethylidene)-2,3-dihydro-1H-inden-1-one
In the title compound, C(14)H(10)O(2), the five-membered ring of the inden-1-one residue is almost planar (r.m.s. deviation = 0.035 Å). A twist about the single bond linking the two residues is evident [C—C—C—C torsion angle = −13.2 (5)°]. The three-dimensional architecture is stabilized by C—H⋯O (i...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344023/ https://www.ncbi.nlm.nih.gov/pubmed/22589932 http://dx.doi.org/10.1107/S1600536812010501 |
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author | Asiri, Abdullah M. Faidallah, Hassan M. Al-Nemari, Khulud F. Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Asiri, Abdullah M. Faidallah, Hassan M. Al-Nemari, Khulud F. Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Asiri, Abdullah M. |
collection | PubMed |
description | In the title compound, C(14)H(10)O(2), the five-membered ring of the inden-1-one residue is almost planar (r.m.s. deviation = 0.035 Å). A twist about the single bond linking the two residues is evident [C—C—C—C torsion angle = −13.2 (5)°]. The three-dimensional architecture is stabilized by C—H⋯O (involving the trifurcated carbonyl O atom), C—H⋯π and π–π interactions [between the five- and six-membered rings of inden-1-one residues; ring centroid–centroid distance = 3.7983 (17) Å]. The sample studied was a non-merohedral twin; the minor component refined to approximately 36%. |
format | Online Article Text |
id | pubmed-3344023 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33440232012-05-15 (2E)-2-(Furan-2-ylmethylidene)-2,3-dihydro-1H-inden-1-one Asiri, Abdullah M. Faidallah, Hassan M. Al-Nemari, Khulud F. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(10)O(2), the five-membered ring of the inden-1-one residue is almost planar (r.m.s. deviation = 0.035 Å). A twist about the single bond linking the two residues is evident [C—C—C—C torsion angle = −13.2 (5)°]. The three-dimensional architecture is stabilized by C—H⋯O (involving the trifurcated carbonyl O atom), C—H⋯π and π–π interactions [between the five- and six-membered rings of inden-1-one residues; ring centroid–centroid distance = 3.7983 (17) Å]. The sample studied was a non-merohedral twin; the minor component refined to approximately 36%. International Union of Crystallography 2012-03-14 /pmc/articles/PMC3344023/ /pubmed/22589932 http://dx.doi.org/10.1107/S1600536812010501 Text en © Asiri et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Asiri, Abdullah M. Faidallah, Hassan M. Al-Nemari, Khulud F. Ng, Seik Weng Tiekink, Edward R. T. (2E)-2-(Furan-2-ylmethylidene)-2,3-dihydro-1H-inden-1-one |
title | (2E)-2-(Furan-2-ylmethylidene)-2,3-dihydro-1H-inden-1-one |
title_full | (2E)-2-(Furan-2-ylmethylidene)-2,3-dihydro-1H-inden-1-one |
title_fullStr | (2E)-2-(Furan-2-ylmethylidene)-2,3-dihydro-1H-inden-1-one |
title_full_unstemmed | (2E)-2-(Furan-2-ylmethylidene)-2,3-dihydro-1H-inden-1-one |
title_short | (2E)-2-(Furan-2-ylmethylidene)-2,3-dihydro-1H-inden-1-one |
title_sort | (2e)-2-(furan-2-ylmethylidene)-2,3-dihydro-1h-inden-1-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344023/ https://www.ncbi.nlm.nih.gov/pubmed/22589932 http://dx.doi.org/10.1107/S1600536812010501 |
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