4-Fluoro-2-[(3-methyl­phen­yl)imino­meth­yl]phenol

The title compound, C(14)H(12)FNO, crystallizes as the trans phenol–imine tautomer. The two benzene rings are essentially coplanar, being inclined to one another by 9.28 (7)°. This is at least in part due to the intra­molecular O—H⋯N hydrogen bond between the hy­droxy O atom and the imine N atom. Th...

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Detalles Bibliográficos
Autores principales: Brink, Alice, Visser, Hendrik G., Roodt, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344028/
https://www.ncbi.nlm.nih.gov/pubmed/22589937
http://dx.doi.org/10.1107/S1600536812010513
Descripción
Sumario:The title compound, C(14)H(12)FNO, crystallizes as the trans phenol–imine tautomer. The two benzene rings are essentially coplanar, being inclined to one another by 9.28 (7)°. This is at least in part due to the intra­molecular O—H⋯N hydrogen bond between the hy­droxy O atom and the imine N atom. The crystal structure is stabilized by an array of weak C—H⋯O and C—H⋯F inter­actions, which link the mol­ecules into a stable three-dimensional network.

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