4-Fluoro-2-[(3-methyl­phen­yl)imino­meth­yl]phenol

The title compound, C(14)H(12)FNO, crystallizes as the trans phenol–imine tautomer. The two benzene rings are essentially coplanar, being inclined to one another by 9.28 (7)°. This is at least in part due to the intra­molecular O—H⋯N hydrogen bond between the hy­droxy O atom and the imine N atom. Th...

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Detalles Bibliográficos
Autores principales: Brink, Alice, Visser, Hendrik G., Roodt, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344028/
https://www.ncbi.nlm.nih.gov/pubmed/22589937
http://dx.doi.org/10.1107/S1600536812010513
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author Brink, Alice
Visser, Hendrik G.
Roodt, Andreas
author_facet Brink, Alice
Visser, Hendrik G.
Roodt, Andreas
author_sort Brink, Alice
collection PubMed
description The title compound, C(14)H(12)FNO, crystallizes as the trans phenol–imine tautomer. The two benzene rings are essentially coplanar, being inclined to one another by 9.28 (7)°. This is at least in part due to the intra­molecular O—H⋯N hydrogen bond between the hy­droxy O atom and the imine N atom. The crystal structure is stabilized by an array of weak C—H⋯O and C—H⋯F inter­actions, which link the mol­ecules into a stable three-dimensional network.
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spelling pubmed-33440282012-05-15 4-Fluoro-2-[(3-methyl­phen­yl)imino­meth­yl]phenol Brink, Alice Visser, Hendrik G. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(12)FNO, crystallizes as the trans phenol–imine tautomer. The two benzene rings are essentially coplanar, being inclined to one another by 9.28 (7)°. This is at least in part due to the intra­molecular O—H⋯N hydrogen bond between the hy­droxy O atom and the imine N atom. The crystal structure is stabilized by an array of weak C—H⋯O and C—H⋯F inter­actions, which link the mol­ecules into a stable three-dimensional network. International Union of Crystallography 2012-03-14 /pmc/articles/PMC3344028/ /pubmed/22589937 http://dx.doi.org/10.1107/S1600536812010513 Text en © Brink et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Brink, Alice
Visser, Hendrik G.
Roodt, Andreas
4-Fluoro-2-[(3-methyl­phen­yl)imino­meth­yl]phenol
title 4-Fluoro-2-[(3-methyl­phen­yl)imino­meth­yl]phenol
title_full 4-Fluoro-2-[(3-methyl­phen­yl)imino­meth­yl]phenol
title_fullStr 4-Fluoro-2-[(3-methyl­phen­yl)imino­meth­yl]phenol
title_full_unstemmed 4-Fluoro-2-[(3-methyl­phen­yl)imino­meth­yl]phenol
title_short 4-Fluoro-2-[(3-methyl­phen­yl)imino­meth­yl]phenol
title_sort 4-fluoro-2-[(3-methyl­phen­yl)imino­meth­yl]phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344028/
https://www.ncbi.nlm.nih.gov/pubmed/22589937
http://dx.doi.org/10.1107/S1600536812010513
work_keys_str_mv AT brinkalice 4fluoro23methylphenyliminomethylphenol
AT visserhendrikg 4fluoro23methylphenyliminomethylphenol
AT roodtandreas 4fluoro23methylphenyliminomethylphenol

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