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8-O-Acetyl-8-epi-9-de­oxygoniopypyrone

The title compound (systematic name: 7-oxo-3-phenyl-2,6-dioxabicyclo­[3.3.1]nonan-4-yl acetate), C(15)H(16)O(5), is a styryllactone derivative which was isolated from Goniothalamus macrophyllus. The mol­ecule has two fused rings consisting of a tetra­hydro-2H-pyran and a lactone ring, with the benze...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Chantrapromma, Suchada, Prawat, Uma, Boonnak, Nawong, Razak, Ibrahim Abdul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344029/
https://www.ncbi.nlm.nih.gov/pubmed/22589938
http://dx.doi.org/10.1107/S1600536812010483
Descripción
Sumario:The title compound (systematic name: 7-oxo-3-phenyl-2,6-dioxabicyclo­[3.3.1]nonan-4-yl acetate), C(15)H(16)O(5), is a styryllactone derivative which was isolated from Goniothalamus macrophyllus. The mol­ecule has two fused rings consisting of a tetra­hydro-2H-pyran and a lactone ring, with the benzene ring and the acetyl group attached to the tetra­hydro-2H-pyran ring. The tetra­hydro-2H-pyran ring is in a standard chair conformation, whereas the lactone ring is in an envelope conformation. In the crystal, mol­ecules are linked by weak C—H⋯O inter­actions into sheets parallel to the ac plane. Weak C—H⋯π inter­actions are also observed.