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N,N′-Diethyl-N,N′-diphenylpyridine-2,6-dicarboxamide
The asymmetric unit of the title compound, C(23)H(23)N(3)O(2), contains two molecules in both of which, one amide N atom is in a syn position with respect to the pyridine N atom, while the other amide N atom is in an anti position (the syn--anti conformation). There are minor conformational differe...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344051/ https://www.ncbi.nlm.nih.gov/pubmed/22589960 http://dx.doi.org/10.1107/S1600536812009026 |
Sumario: | The asymmetric unit of the title compound, C(23)H(23)N(3)O(2), contains two molecules in both of which, one amide N atom is in a syn position with respect to the pyridine N atom, while the other amide N atom is in an anti position (the syn--anti conformation). There are minor conformational differences between the two molecules, as reflected in the N(pyridine)—C—C—N(amide) torsion angles of −44.9 (3) and 136.0 (2)° for one molecule and 43.5 (3) and −131.1 (2)° for the other molecule. However, the two molecules show significant differences in the orientation of an ethyl group, with corresponding C—C—N—C torsion angles of 86.6 (3)° for one molecule and 79.6 (3)° for the other molecule. In the crystal, molecules are linked by weak C—H⋯O hydrogen bonds, forming a three-dimensional supramolecular network. |
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