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N,N′-Diethyl-N,N′-diphenyl­pyridine-2,6-dicarboxamide

The asymmetric unit of the title compound, C(23)H(23)N(3)O(2), contains two mol­ecules in both of which, one amide N atom is in a syn position with respect to the pyridine N atom, while the other amide N atom is in an anti position (the syn--anti conformation). There are minor conformational differe...

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Autores principales: Klepetářová, Blanka, Makrlík, Emanuel, Babain, Vasily A., Kašička, Václav
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344051/
https://www.ncbi.nlm.nih.gov/pubmed/22589960
http://dx.doi.org/10.1107/S1600536812009026
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author Klepetářová, Blanka
Makrlík, Emanuel
Babain, Vasily A.
Kašička, Václav
author_facet Klepetářová, Blanka
Makrlík, Emanuel
Babain, Vasily A.
Kašička, Václav
author_sort Klepetářová, Blanka
collection PubMed
description The asymmetric unit of the title compound, C(23)H(23)N(3)O(2), contains two mol­ecules in both of which, one amide N atom is in a syn position with respect to the pyridine N atom, while the other amide N atom is in an anti position (the syn--anti conformation). There are minor conformational differences between the two mol­ecules, as reflected in the N(pyridine)—C—C—N(amide) torsion angles of −44.9 (3) and 136.0 (2)° for one mol­ecule and 43.5 (3) and −131.1 (2)° for the other mol­ecule. However, the two mol­ecules show significant differences in the orientation of an ethyl group, with corresponding C—C—N—C torsion angles of 86.6 (3)° for one mol­ecule and 79.6 (3)° for the other mol­ecule. In the crystal, mol­ecules are linked by weak C—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network.
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spelling pubmed-33440512012-05-15 N,N′-Diethyl-N,N′-diphenyl­pyridine-2,6-dicarboxamide Klepetářová, Blanka Makrlík, Emanuel Babain, Vasily A. Kašička, Václav Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(23)H(23)N(3)O(2), contains two mol­ecules in both of which, one amide N atom is in a syn position with respect to the pyridine N atom, while the other amide N atom is in an anti position (the syn--anti conformation). There are minor conformational differences between the two mol­ecules, as reflected in the N(pyridine)—C—C—N(amide) torsion angles of −44.9 (3) and 136.0 (2)° for one mol­ecule and 43.5 (3) and −131.1 (2)° for the other mol­ecule. However, the two mol­ecules show significant differences in the orientation of an ethyl group, with corresponding C—C—N—C torsion angles of 86.6 (3)° for one mol­ecule and 79.6 (3)° for the other mol­ecule. In the crystal, mol­ecules are linked by weak C—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network. International Union of Crystallography 2012-03-17 /pmc/articles/PMC3344051/ /pubmed/22589960 http://dx.doi.org/10.1107/S1600536812009026 Text en © Klepetářová et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Klepetářová, Blanka
Makrlík, Emanuel
Babain, Vasily A.
Kašička, Václav
N,N′-Diethyl-N,N′-diphenyl­pyridine-2,6-dicarboxamide
title N,N′-Diethyl-N,N′-diphenyl­pyridine-2,6-dicarboxamide
title_full N,N′-Diethyl-N,N′-diphenyl­pyridine-2,6-dicarboxamide
title_fullStr N,N′-Diethyl-N,N′-diphenyl­pyridine-2,6-dicarboxamide
title_full_unstemmed N,N′-Diethyl-N,N′-diphenyl­pyridine-2,6-dicarboxamide
title_short N,N′-Diethyl-N,N′-diphenyl­pyridine-2,6-dicarboxamide
title_sort n,n′-diethyl-n,n′-diphenyl­pyridine-2,6-dicarboxamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344051/
https://www.ncbi.nlm.nih.gov/pubmed/22589960
http://dx.doi.org/10.1107/S1600536812009026
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