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N,N′-Diethyl-N,N′-diphenylpyridine-2,6-dicarboxamide
The asymmetric unit of the title compound, C(23)H(23)N(3)O(2), contains two molecules in both of which, one amide N atom is in a syn position with respect to the pyridine N atom, while the other amide N atom is in an anti position (the syn--anti conformation). There are minor conformational differe...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344051/ https://www.ncbi.nlm.nih.gov/pubmed/22589960 http://dx.doi.org/10.1107/S1600536812009026 |
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author | Klepetářová, Blanka Makrlík, Emanuel Babain, Vasily A. Kašička, Václav |
author_facet | Klepetářová, Blanka Makrlík, Emanuel Babain, Vasily A. Kašička, Václav |
author_sort | Klepetářová, Blanka |
collection | PubMed |
description | The asymmetric unit of the title compound, C(23)H(23)N(3)O(2), contains two molecules in both of which, one amide N atom is in a syn position with respect to the pyridine N atom, while the other amide N atom is in an anti position (the syn--anti conformation). There are minor conformational differences between the two molecules, as reflected in the N(pyridine)—C—C—N(amide) torsion angles of −44.9 (3) and 136.0 (2)° for one molecule and 43.5 (3) and −131.1 (2)° for the other molecule. However, the two molecules show significant differences in the orientation of an ethyl group, with corresponding C—C—N—C torsion angles of 86.6 (3)° for one molecule and 79.6 (3)° for the other molecule. In the crystal, molecules are linked by weak C—H⋯O hydrogen bonds, forming a three-dimensional supramolecular network. |
format | Online Article Text |
id | pubmed-3344051 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33440512012-05-15 N,N′-Diethyl-N,N′-diphenylpyridine-2,6-dicarboxamide Klepetářová, Blanka Makrlík, Emanuel Babain, Vasily A. Kašička, Václav Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(23)H(23)N(3)O(2), contains two molecules in both of which, one amide N atom is in a syn position with respect to the pyridine N atom, while the other amide N atom is in an anti position (the syn--anti conformation). There are minor conformational differences between the two molecules, as reflected in the N(pyridine)—C—C—N(amide) torsion angles of −44.9 (3) and 136.0 (2)° for one molecule and 43.5 (3) and −131.1 (2)° for the other molecule. However, the two molecules show significant differences in the orientation of an ethyl group, with corresponding C—C—N—C torsion angles of 86.6 (3)° for one molecule and 79.6 (3)° for the other molecule. In the crystal, molecules are linked by weak C—H⋯O hydrogen bonds, forming a three-dimensional supramolecular network. International Union of Crystallography 2012-03-17 /pmc/articles/PMC3344051/ /pubmed/22589960 http://dx.doi.org/10.1107/S1600536812009026 Text en © Klepetářová et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Klepetářová, Blanka Makrlík, Emanuel Babain, Vasily A. Kašička, Václav N,N′-Diethyl-N,N′-diphenylpyridine-2,6-dicarboxamide |
title |
N,N′-Diethyl-N,N′-diphenylpyridine-2,6-dicarboxamide |
title_full |
N,N′-Diethyl-N,N′-diphenylpyridine-2,6-dicarboxamide |
title_fullStr |
N,N′-Diethyl-N,N′-diphenylpyridine-2,6-dicarboxamide |
title_full_unstemmed |
N,N′-Diethyl-N,N′-diphenylpyridine-2,6-dicarboxamide |
title_short |
N,N′-Diethyl-N,N′-diphenylpyridine-2,6-dicarboxamide |
title_sort | n,n′-diethyl-n,n′-diphenylpyridine-2,6-dicarboxamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344051/ https://www.ncbi.nlm.nih.gov/pubmed/22589960 http://dx.doi.org/10.1107/S1600536812009026 |
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