(3aR*,6S*,7aR*)-7a-Chloro-6-methyl-2-(4-methyl­phenyl­sulfon­yl)-2,3,3a,6,7,7a-hexa­hydro-3a,6-ep­oxy-1H-isoindole

In the title compound, C(16)H(18)ClNO(3)S, the six-membered ring has a boat conformation. The two five-membered rings with the bridging O atom adopt envelope conformations, whereas the N-containing five-membered ring adopts a twisted conformation. In the crystal, C—H⋯O hydrogen bonds link the mol­ec...

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Autores principales: Temel, Ersin, Demircan, Aydın, Beyazova, Gözde, Büyükgüngör, Orhan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344053/
https://www.ncbi.nlm.nih.gov/pubmed/22589962
http://dx.doi.org/10.1107/S1600536812009658
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author Temel, Ersin
Demircan, Aydın
Beyazova, Gözde
Büyükgüngör, Orhan
author_facet Temel, Ersin
Demircan, Aydın
Beyazova, Gözde
Büyükgüngör, Orhan
author_sort Temel, Ersin
collection PubMed
description In the title compound, C(16)H(18)ClNO(3)S, the six-membered ring has a boat conformation. The two five-membered rings with the bridging O atom adopt envelope conformations, whereas the N-containing five-membered ring adopts a twisted conformation. In the crystal, C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network.
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spelling pubmed-33440532012-05-15 (3aR*,6S*,7aR*)-7a-Chloro-6-methyl-2-(4-methyl­phenyl­sulfon­yl)-2,3,3a,6,7,7a-hexa­hydro-3a,6-ep­oxy-1H-isoindole Temel, Ersin Demircan, Aydın Beyazova, Gözde Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(18)ClNO(3)S, the six-membered ring has a boat conformation. The two five-membered rings with the bridging O atom adopt envelope conformations, whereas the N-containing five-membered ring adopts a twisted conformation. In the crystal, C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. International Union of Crystallography 2012-03-17 /pmc/articles/PMC3344053/ /pubmed/22589962 http://dx.doi.org/10.1107/S1600536812009658 Text en © Temel et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Temel, Ersin
Demircan, Aydın
Beyazova, Gözde
Büyükgüngör, Orhan
(3aR*,6S*,7aR*)-7a-Chloro-6-methyl-2-(4-methyl­phenyl­sulfon­yl)-2,3,3a,6,7,7a-hexa­hydro-3a,6-ep­oxy-1H-isoindole
title (3aR*,6S*,7aR*)-7a-Chloro-6-methyl-2-(4-methyl­phenyl­sulfon­yl)-2,3,3a,6,7,7a-hexa­hydro-3a,6-ep­oxy-1H-isoindole
title_full (3aR*,6S*,7aR*)-7a-Chloro-6-methyl-2-(4-methyl­phenyl­sulfon­yl)-2,3,3a,6,7,7a-hexa­hydro-3a,6-ep­oxy-1H-isoindole
title_fullStr (3aR*,6S*,7aR*)-7a-Chloro-6-methyl-2-(4-methyl­phenyl­sulfon­yl)-2,3,3a,6,7,7a-hexa­hydro-3a,6-ep­oxy-1H-isoindole
title_full_unstemmed (3aR*,6S*,7aR*)-7a-Chloro-6-methyl-2-(4-methyl­phenyl­sulfon­yl)-2,3,3a,6,7,7a-hexa­hydro-3a,6-ep­oxy-1H-isoindole
title_short (3aR*,6S*,7aR*)-7a-Chloro-6-methyl-2-(4-methyl­phenyl­sulfon­yl)-2,3,3a,6,7,7a-hexa­hydro-3a,6-ep­oxy-1H-isoindole
title_sort (3ar*,6s*,7ar*)-7a-chloro-6-methyl-2-(4-methyl­phenyl­sulfon­yl)-2,3,3a,6,7,7a-hexa­hydro-3a,6-ep­oxy-1h-isoindole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344053/
https://www.ncbi.nlm.nih.gov/pubmed/22589962
http://dx.doi.org/10.1107/S1600536812009658
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