6,6-Dimethyl-2H,5H,6H,7H-1,3-dithiolo[4,5-f][1,5,3]dithia­silepin-2-one

In the structure of the title compound, C(7)H(10)OS(4)Si, the carbonyl O atom lies in the plane of the five-membered dithiole ring with a deviation of only 0.022 (2) Å. The seven-membered ring adopts a chair conformation. The crystal packing is stabilized by S⋯O [3.096 (4) Å] and S⋯S [3.620 (4) Å] c...

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Detalles Bibliográficos
Autores principales: Li, Hongqi, Zhang, Xuebin, Zhang, Zhongbao, Chen, Zhen, Peng, Jiajian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344068/
https://www.ncbi.nlm.nih.gov/pubmed/22589977
http://dx.doi.org/10.1107/S1600536812011142
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author Li, Hongqi
Zhang, Xuebin
Zhang, Zhongbao
Chen, Zhen
Peng, Jiajian
author_facet Li, Hongqi
Zhang, Xuebin
Zhang, Zhongbao
Chen, Zhen
Peng, Jiajian
author_sort Li, Hongqi
collection PubMed
description In the structure of the title compound, C(7)H(10)OS(4)Si, the carbonyl O atom lies in the plane of the five-membered dithiole ring with a deviation of only 0.022 (2) Å. The seven-membered ring adopts a chair conformation. The crystal packing is stabilized by S⋯O [3.096 (4) Å] and S⋯S [3.620 (4) Å] contacts, together with C—H⋯S inter­actions.
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spelling pubmed-33440682012-05-15 6,6-Dimethyl-2H,5H,6H,7H-1,3-dithiolo[4,5-f][1,5,3]dithia­silepin-2-one Li, Hongqi Zhang, Xuebin Zhang, Zhongbao Chen, Zhen Peng, Jiajian Acta Crystallogr Sect E Struct Rep Online Organic Papers In the structure of the title compound, C(7)H(10)OS(4)Si, the carbonyl O atom lies in the plane of the five-membered dithiole ring with a deviation of only 0.022 (2) Å. The seven-membered ring adopts a chair conformation. The crystal packing is stabilized by S⋯O [3.096 (4) Å] and S⋯S [3.620 (4) Å] contacts, together with C—H⋯S inter­actions. International Union of Crystallography 2012-03-21 /pmc/articles/PMC3344068/ /pubmed/22589977 http://dx.doi.org/10.1107/S1600536812011142 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Hongqi
Zhang, Xuebin
Zhang, Zhongbao
Chen, Zhen
Peng, Jiajian
6,6-Dimethyl-2H,5H,6H,7H-1,3-dithiolo[4,5-f][1,5,3]dithia­silepin-2-one
title 6,6-Dimethyl-2H,5H,6H,7H-1,3-dithiolo[4,5-f][1,5,3]dithia­silepin-2-one
title_full 6,6-Dimethyl-2H,5H,6H,7H-1,3-dithiolo[4,5-f][1,5,3]dithia­silepin-2-one
title_fullStr 6,6-Dimethyl-2H,5H,6H,7H-1,3-dithiolo[4,5-f][1,5,3]dithia­silepin-2-one
title_full_unstemmed 6,6-Dimethyl-2H,5H,6H,7H-1,3-dithiolo[4,5-f][1,5,3]dithia­silepin-2-one
title_short 6,6-Dimethyl-2H,5H,6H,7H-1,3-dithiolo[4,5-f][1,5,3]dithia­silepin-2-one
title_sort 6,6-dimethyl-2h,5h,6h,7h-1,3-dithiolo[4,5-f][1,5,3]dithia­silepin-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344068/
https://www.ncbi.nlm.nih.gov/pubmed/22589977
http://dx.doi.org/10.1107/S1600536812011142
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