2,4-Bis(diphenyl­phosphan­yl)-1,1,2,3,3,4-hexa­phenyl-1,3-diphospha-2,4-dibora­cyclo­butane tetra­hydro­furan sesqui­solvate

In the title compound, C(60)H(50)B(2)P(4)·1.5C(4)H(8)O, the diphospha­diborane mol­ecule lies on an inversion centre, whereas the disordered tetra­hydro­furan solvent mol­ecule is in a general position with a partial occupancy of 0.75. The diphosphadiborane mol­ecule consists of an ideal planar four...

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Detalles Bibliográficos
Autores principales: Peulecke, Normen, Müller, Bernd H., Spannenberg, Anke, Rosenthal, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344071/
https://www.ncbi.nlm.nih.gov/pubmed/22589980
http://dx.doi.org/10.1107/S1600536812011361
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author Peulecke, Normen
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
author_facet Peulecke, Normen
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
author_sort Peulecke, Normen
collection PubMed
description In the title compound, C(60)H(50)B(2)P(4)·1.5C(4)H(8)O, the diphospha­diborane mol­ecule lies on an inversion centre, whereas the disordered tetra­hydro­furan solvent mol­ecule is in a general position with a partial occupancy of 0.75. The diphosphadiborane mol­ecule consists of an ideal planar four-membered B(2)P(2) ring with an additional phenyl and a –PPh(2) group attached to each B atom.
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spelling pubmed-33440712012-05-15 2,4-Bis(diphenyl­phosphan­yl)-1,1,2,3,3,4-hexa­phenyl-1,3-diphospha-2,4-dibora­cyclo­butane tetra­hydro­furan sesqui­solvate Peulecke, Normen Müller, Bernd H. Spannenberg, Anke Rosenthal, Uwe Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(60)H(50)B(2)P(4)·1.5C(4)H(8)O, the diphospha­diborane mol­ecule lies on an inversion centre, whereas the disordered tetra­hydro­furan solvent mol­ecule is in a general position with a partial occupancy of 0.75. The diphosphadiborane mol­ecule consists of an ideal planar four-membered B(2)P(2) ring with an additional phenyl and a –PPh(2) group attached to each B atom. International Union of Crystallography 2012-03-21 /pmc/articles/PMC3344071/ /pubmed/22589980 http://dx.doi.org/10.1107/S1600536812011361 Text en © Peulecke et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Peulecke, Normen
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
2,4-Bis(diphenyl­phosphan­yl)-1,1,2,3,3,4-hexa­phenyl-1,3-diphospha-2,4-dibora­cyclo­butane tetra­hydro­furan sesqui­solvate
title 2,4-Bis(diphenyl­phosphan­yl)-1,1,2,3,3,4-hexa­phenyl-1,3-diphospha-2,4-dibora­cyclo­butane tetra­hydro­furan sesqui­solvate
title_full 2,4-Bis(diphenyl­phosphan­yl)-1,1,2,3,3,4-hexa­phenyl-1,3-diphospha-2,4-dibora­cyclo­butane tetra­hydro­furan sesqui­solvate
title_fullStr 2,4-Bis(diphenyl­phosphan­yl)-1,1,2,3,3,4-hexa­phenyl-1,3-diphospha-2,4-dibora­cyclo­butane tetra­hydro­furan sesqui­solvate
title_full_unstemmed 2,4-Bis(diphenyl­phosphan­yl)-1,1,2,3,3,4-hexa­phenyl-1,3-diphospha-2,4-dibora­cyclo­butane tetra­hydro­furan sesqui­solvate
title_short 2,4-Bis(diphenyl­phosphan­yl)-1,1,2,3,3,4-hexa­phenyl-1,3-diphospha-2,4-dibora­cyclo­butane tetra­hydro­furan sesqui­solvate
title_sort 2,4-bis(diphenyl­phosphan­yl)-1,1,2,3,3,4-hexa­phenyl-1,3-diphospha-2,4-dibora­cyclo­butane tetra­hydro­furan sesqui­solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344071/
https://www.ncbi.nlm.nih.gov/pubmed/22589980
http://dx.doi.org/10.1107/S1600536812011361
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AT spannenberganke 24bisdiphenylphosphanyl112334hexaphenyl13diphospha24diboracyclobutanetetrahydrofuransesquisolvate
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