Tetra­methyl N,N′-(2,2,3,3,4,4-hexa­fluoro-1,5-dioxopentane-1,5-di­yl)bis­(phospho­ramidate)

The mol­ecule of the title compound, C(9)H(14)F(6)N(2)O(8)P(2), lies on a twofold rotation axis that passes through the middle C atom of the three-atom fluoro­methyl­ene unit. The carbonyl and phosphoryl groups are in an antiperiplanar conformation. In the crystal, N—H⋯O=P hydrogen bonds link the mo...

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Autores principales: Trush, Victor A., Gubina, Kateryna E., Gumeniuk, Yaroslav O., Sliva, Tetyana Yu., Konovalova, Irina S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344073/
https://www.ncbi.nlm.nih.gov/pubmed/22589982
http://dx.doi.org/10.1107/S1600536812011191
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author Trush, Victor A.
Gubina, Kateryna E.
Gumeniuk, Yaroslav O.
Sliva, Tetyana Yu.
Konovalova, Irina S.
author_facet Trush, Victor A.
Gubina, Kateryna E.
Gumeniuk, Yaroslav O.
Sliva, Tetyana Yu.
Konovalova, Irina S.
author_sort Trush, Victor A.
collection PubMed
description The mol­ecule of the title compound, C(9)H(14)F(6)N(2)O(8)P(2), lies on a twofold rotation axis that passes through the middle C atom of the three-atom fluoro­methyl­ene unit. The carbonyl and phosphoryl groups are in an antiperiplanar conformation. In the crystal, N—H⋯O=P hydrogen bonds link the mol­ecules into polymeric chains parallel to the c axis.
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spelling pubmed-33440732012-05-15 Tetra­methyl N,N′-(2,2,3,3,4,4-hexa­fluoro-1,5-dioxopentane-1,5-di­yl)bis­(phospho­ramidate) Trush, Victor A. Gubina, Kateryna E. Gumeniuk, Yaroslav O. Sliva, Tetyana Yu. Konovalova, Irina S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(9)H(14)F(6)N(2)O(8)P(2), lies on a twofold rotation axis that passes through the middle C atom of the three-atom fluoro­methyl­ene unit. The carbonyl and phosphoryl groups are in an antiperiplanar conformation. In the crystal, N—H⋯O=P hydrogen bonds link the mol­ecules into polymeric chains parallel to the c axis. International Union of Crystallography 2012-03-21 /pmc/articles/PMC3344073/ /pubmed/22589982 http://dx.doi.org/10.1107/S1600536812011191 Text en © Trush et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Trush, Victor A.
Gubina, Kateryna E.
Gumeniuk, Yaroslav O.
Sliva, Tetyana Yu.
Konovalova, Irina S.
Tetra­methyl N,N′-(2,2,3,3,4,4-hexa­fluoro-1,5-dioxopentane-1,5-di­yl)bis­(phospho­ramidate)
title Tetra­methyl N,N′-(2,2,3,3,4,4-hexa­fluoro-1,5-dioxopentane-1,5-di­yl)bis­(phospho­ramidate)
title_full Tetra­methyl N,N′-(2,2,3,3,4,4-hexa­fluoro-1,5-dioxopentane-1,5-di­yl)bis­(phospho­ramidate)
title_fullStr Tetra­methyl N,N′-(2,2,3,3,4,4-hexa­fluoro-1,5-dioxopentane-1,5-di­yl)bis­(phospho­ramidate)
title_full_unstemmed Tetra­methyl N,N′-(2,2,3,3,4,4-hexa­fluoro-1,5-dioxopentane-1,5-di­yl)bis­(phospho­ramidate)
title_short Tetra­methyl N,N′-(2,2,3,3,4,4-hexa­fluoro-1,5-dioxopentane-1,5-di­yl)bis­(phospho­ramidate)
title_sort tetra­methyl n,n′-(2,2,3,3,4,4-hexa­fluoro-1,5-dioxopentane-1,5-di­yl)bis­(phospho­ramidate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344073/
https://www.ncbi.nlm.nih.gov/pubmed/22589982
http://dx.doi.org/10.1107/S1600536812011191
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