Methyl 2,2-dimeth­oxy-5,5-bis­(methyl­sulfan­yl)-3-oxopent-4-enedithio­ate

In the title mol­ecule, C(10)H(16)O(3)S(4), a short intra­molecular S⋯O(=C) distance [2.726 (2) Å] indicates the presence of a nonbonding attractive inter­action. In the crystal, mol­ecules are linked into centrosymmetric dimers via weak inter­molecular C—H⋯O and S⋯S [3.405 (3) Å] inter­actions. The...

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Detalles Bibliográficos
Autor principal: Ghorbani, Mohammad Hassan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344079/
https://www.ncbi.nlm.nih.gov/pubmed/22589988
http://dx.doi.org/10.1107/S1600536812011282
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author Ghorbani, Mohammad Hassan
author_facet Ghorbani, Mohammad Hassan
author_sort Ghorbani, Mohammad Hassan
collection PubMed
description In the title mol­ecule, C(10)H(16)O(3)S(4), a short intra­molecular S⋯O(=C) distance [2.726 (2) Å] indicates the presence of a nonbonding attractive inter­action. In the crystal, mol­ecules are linked into centrosymmetric dimers via weak inter­molecular C—H⋯O and S⋯S [3.405 (3) Å] inter­actions. These dimers are linked by further weak C—H⋯O inter­actions into columns along the a axis.
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spelling pubmed-33440792012-05-15 Methyl 2,2-dimeth­oxy-5,5-bis­(methyl­sulfan­yl)-3-oxopent-4-enedithio­ate Ghorbani, Mohammad Hassan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(10)H(16)O(3)S(4), a short intra­molecular S⋯O(=C) distance [2.726 (2) Å] indicates the presence of a nonbonding attractive inter­action. In the crystal, mol­ecules are linked into centrosymmetric dimers via weak inter­molecular C—H⋯O and S⋯S [3.405 (3) Å] inter­actions. These dimers are linked by further weak C—H⋯O inter­actions into columns along the a axis. International Union of Crystallography 2012-03-21 /pmc/articles/PMC3344079/ /pubmed/22589988 http://dx.doi.org/10.1107/S1600536812011282 Text en © Mohammad Hassan Ghorbani 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ghorbani, Mohammad Hassan
Methyl 2,2-dimeth­oxy-5,5-bis­(methyl­sulfan­yl)-3-oxopent-4-enedithio­ate
title Methyl 2,2-dimeth­oxy-5,5-bis­(methyl­sulfan­yl)-3-oxopent-4-enedithio­ate
title_full Methyl 2,2-dimeth­oxy-5,5-bis­(methyl­sulfan­yl)-3-oxopent-4-enedithio­ate
title_fullStr Methyl 2,2-dimeth­oxy-5,5-bis­(methyl­sulfan­yl)-3-oxopent-4-enedithio­ate
title_full_unstemmed Methyl 2,2-dimeth­oxy-5,5-bis­(methyl­sulfan­yl)-3-oxopent-4-enedithio­ate
title_short Methyl 2,2-dimeth­oxy-5,5-bis­(methyl­sulfan­yl)-3-oxopent-4-enedithio­ate
title_sort methyl 2,2-dimeth­oxy-5,5-bis­(methyl­sulfan­yl)-3-oxopent-4-enedithio­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344079/
https://www.ncbi.nlm.nih.gov/pubmed/22589988
http://dx.doi.org/10.1107/S1600536812011282
work_keys_str_mv AT ghorbanimohammadhassan methyl22dimethoxy55bismethylsulfanyl3oxopent4enedithioate

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