N-(2-Amino­pyridin-3-yl)-4-methyl-N-(4-methyl­phenyl­sulfon­yl)benzene­sulfonamide

The title compound, C(19)H(19)N(3)O(4)S(2), was prepared by the reaction of 2,3-diamino­pyridine with tosyl chloride in a mixture of dichloro­methane–pyridine as solvent. In the crystal, mol­ecules associate via pairs of N—H⋯N hydrogen bonds, forming a centrosymmetric eight-membered {⋯HNCN}(2) synth...

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Detalles Bibliográficos
Autores principales: Taher, Abu, Smith, Vincent J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344082/
https://www.ncbi.nlm.nih.gov/pubmed/22606085
http://dx.doi.org/10.1107/S1600536812010872
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author Taher, Abu
Smith, Vincent J.
author_facet Taher, Abu
Smith, Vincent J.
author_sort Taher, Abu
collection PubMed
description The title compound, C(19)H(19)N(3)O(4)S(2), was prepared by the reaction of 2,3-diamino­pyridine with tosyl chloride in a mixture of dichloro­methane–pyridine as solvent. In the crystal, mol­ecules associate via pairs of N—H⋯N hydrogen bonds, forming a centrosymmetric eight-membered {⋯HNCN}(2) synthon. The dihedral angles between the amino­pyridine ring and the tosyl benzene rings are 50.01 (6) and 32.01 (4)°.
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spelling pubmed-33440822012-05-17 N-(2-Amino­pyridin-3-yl)-4-methyl-N-(4-methyl­phenyl­sulfon­yl)benzene­sulfonamide Taher, Abu Smith, Vincent J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(19)N(3)O(4)S(2), was prepared by the reaction of 2,3-diamino­pyridine with tosyl chloride in a mixture of dichloro­methane–pyridine as solvent. In the crystal, mol­ecules associate via pairs of N—H⋯N hydrogen bonds, forming a centrosymmetric eight-membered {⋯HNCN}(2) synthon. The dihedral angles between the amino­pyridine ring and the tosyl benzene rings are 50.01 (6) and 32.01 (4)°. International Union of Crystallography 2012-03-21 /pmc/articles/PMC3344082/ /pubmed/22606085 http://dx.doi.org/10.1107/S1600536812010872 Text en © Taher and Smith 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Taher, Abu
Smith, Vincent J.
N-(2-Amino­pyridin-3-yl)-4-methyl-N-(4-methyl­phenyl­sulfon­yl)benzene­sulfonamide
title N-(2-Amino­pyridin-3-yl)-4-methyl-N-(4-methyl­phenyl­sulfon­yl)benzene­sulfonamide
title_full N-(2-Amino­pyridin-3-yl)-4-methyl-N-(4-methyl­phenyl­sulfon­yl)benzene­sulfonamide
title_fullStr N-(2-Amino­pyridin-3-yl)-4-methyl-N-(4-methyl­phenyl­sulfon­yl)benzene­sulfonamide
title_full_unstemmed N-(2-Amino­pyridin-3-yl)-4-methyl-N-(4-methyl­phenyl­sulfon­yl)benzene­sulfonamide
title_short N-(2-Amino­pyridin-3-yl)-4-methyl-N-(4-methyl­phenyl­sulfon­yl)benzene­sulfonamide
title_sort n-(2-amino­pyridin-3-yl)-4-methyl-n-(4-methyl­phenyl­sulfon­yl)benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344082/
https://www.ncbi.nlm.nih.gov/pubmed/22606085
http://dx.doi.org/10.1107/S1600536812010872
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